Synthesis and ROMP of Benzothiadiazole Paracyclophane-1,9-Dienes to Donor-Acceptor Alternating Arylenevinylene Copolymers

被引：12
|
作者：
Komanduri, Venukrishnan [1 ]
Tate, Daniel J. [1 ]
Marcial-Hernandez, Raymundo [1 ]
Kumar, Dharam R. [1 ]
Turner, Michael L. [1 ]
机构：
[1] Univ Manchester, Sch Chem, Oxford Rd, Manchester M13 9PL, Lancs, England
来源：
MACROMOLECULES | 2019年 / 52卷 / 18期
基金：
英国工程与自然科学研究理事会;
关键词：
RING-OPENING METATHESIS; CONJUGATED POLYMERS; BLOCK-COPOLYMERS; POLYMERIZATION; PHENYLENEVINYLENE; PERFORMANCE;
D O I：
10.1021/acs.macromol.9b01244
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Dialkoxy- and dialkyl-substituted phenylene benzothiadiazole paracyclophane-1,9-diene monomers undergo living ring-opening metathesis polymerization using ruthenium carbene initiators (G3) to give regularly alternating cis,trans-poly(p-phenylenevinylene) benzothiadiazole copolymers. These polymers can be readily isomerized in dilute solution using visible light to the all-trans polymers. The influence of the polymer microstructure and the phenylene substituents on the optical and electrochemical properties of these polymers is examined.
引用
收藏
页码：7137 / 7144
页数：8
相关论文
共 50 条
  • [31] Structure-property relationship of donor-acceptor type conjugated copolymers with thienoisoquinoline and benzothiadiazole units
    Ha, Jong-Woon
    Moon, Yina
    Yoon, Minho
    Kim, Doyeon
    Hwang, Do-Hoon
    Lee, Jiyoul
    DYES AND PIGMENTS, 2021, 195
  • [32] Synthesis and Properties of Benzodipyrrolidone (BDP)-Based Donor-Acceptor Copolymers
    Chen, Xuegang
    Guo, Kai
    Li, Fanchao
    Qiao, Hongbing
    Liu, Tianyi
    Ye, Yumeng
    Xing, Chao
    Li, Jie
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2015, 52 (07): : 517 - 522
  • [33] The synthesis and purification of amphiphilic conjugated donor-acceptor block copolymers
    Mitchell, Valerie D.
    Wong, Wallace W. H.
    Thelakkat, Mukundan
    Jones, David J.
    POLYMER JOURNAL, 2017, 49 (01) : 155 - 161
  • [34] Donor-Acceptor Block Copolymers: Synthesis and Solar Cell Applications
    Nakabayashi, Kazuhiro
    Mori, Hideharu
    MATERIALS, 2014, 7 (04): : 3274 - 3290
  • [35] Synthesis and characterization of conjugated donor-acceptor copolymers of benzodipyrrolidone and naphthodithiophene
    Dong, Hao
    Shi, Ganhui
    Wang, Xianjian
    Chen, Xuegang
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2022, 59 (06): : 433 - 441
  • [36] DETERMINATION OF THE MONOMER DONOR-ACCEPTOR COMPLEXES PARTICIPATION IN THE ALTERNATING PROPAGATING REACTION BASED ON THE MICROTACTICITY OF THE ALTERNATING COPOLYMERS
    GEORGIEV, GS
    ZUBOV, VP
    POLYMER BULLETIN, 1979, 1 (06) : 441 - 444
  • [37] Benzothiadiazole-based donor-acceptor alternating polymer sensitizers for dye-sensitized solar cells
    Fang, Zhen
    Schanze, Kirk S.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [38] Alternating Donor-Acceptor Arrays from Hexa-peri-hexabenzocoronene and Benzothiadiazole: Synthesis, Optical Properties, and Self-Assembly
    Hinkel, Felix
    Cho, Don
    Pisula, Wojciech
    Baumgarten, Martin
    Muellen, Klaus
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (01) : 86 - 90
  • [39] Semi-random vs Well-Defined Alternating Donor-Acceptor Copolymers
    Braunecker, Wade A.
    Oosterhout, Stefan D.
    Owczarczyk, Zbyslaw R.
    Kopidakis, Nikos
    Ratcliff, Erin L.
    Ginley, David S.
    Olson, Dana C.
    ACS MACRO LETTERS, 2014, 3 (07): : 622 - 627
  • [40] Intrachain energy transfer in silylene-spaced alternating donor-acceptor divinylarene copolymers
    Cheng, YJ
    Hwu, TY
    Hsu, JH
    Luh, TY
    CHEMICAL COMMUNICATIONS, 2002, (17) : 1978 - 1979
12345