Phenyl derivatives of antimony(III, V) and bismuth(III, V) in the presence of palladium salts, as C-phenylating agents for methyl acrylate

被引：6

作者：

Gushchin, AV ^{[1
]}

Moiseev, DV ^{[1
]}

Dodonov, VA ^{[1
]}

机构：

[1] Lobachevskii Nizhni Novgorod State Univ, Nizhnii Novgorod, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 10期

关键词：

D O I：

10.1023/A:1023335617165

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The C-phenylation of methyl acrylate to methyl cynnamate with Ph3Sb, Ph3SbX2 (X = Cl, OAc), Ph3Bi, and Ph3BiX2 (X = OAc, O2CEt) in the presence of PdCl2, Pd(OAc)(2), Li2PdCl4, NaPd(OAc)Cl-2, and Na2Pd(OAc)(2)Cl-2 was studied to show that the reactions with Ph3Sb and Ph3Sb(OAc)(2) are more selective and give higher yields of the target product than those with Ph3Bi and Ph3Bi(OAc)(2), while Ph3M(OAc)(2) are preferred over Ph3M. Copper(II) alkanecarboxylate additives have no effect on the yield of methyl cynnamate in the reactions with Ph3Sb.

引用

页码：1571 / 1575

页数：5

共 49 条

[21] N,C,N-chelated antimony(III), bismuth(III) and tin(IV) derivatives of 1,1'-ferrocenedicarboxylic acid
Jambor, R.
Ruzickova, Z.
Erben, M.
Dostal, L.
INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 76 : 36 - 39
[22] RUTHENIUM(III)-CATALYSED OXIDATION OF METHYL PHENYL SULPHOXIDE BY VANADIUM(V). A KINETIC AND MECHANISTIC STUDY
Babu, B. H.
Reddy, K. R.
Satyanarayana, P. V. V.
OXIDATION COMMUNICATIONS, 2010, 33 (04): : 905 - 912
[23] ENTHALPY OF MIXING OF METHYL-DERIVATIVES OF ELEMENTS OF II, III, V, VI GROUPS
TSVETKOV, VG
KOZYRKIN, BI
FUKIN, KK
GALIULLINA, RF
ZHURNAL OBSHCHEI KHIMII, 1977, 47 (09): : 2155 - 2155
[24] Some reactions and spectroscopic studies of tris(pentafluorophenyl)arsenic and tris(pentafluorophenyl)-antimony(III and V) derivatives
Shukla, SK
Ranjan, A
Saxena, AK
JOURNAL OF FLUORINE CHEMISTRY, 2003, 122 (02) : 165 - 170
[25] Determination of antimony(III) and (V) in natural water by cathodic stripping voltammetry with in-situ plated bismuth film electrode
Ping Zong
Yukio Nagaosa
Microchimica Acta, 2009, 166 : 139 - 144
[26] Determination of antimony(III) and (V) in natural water by cathodic stripping voltammetry with in-situ plated bismuth film electrode
Zong, Ping
Nagaosa, Yukio
MICROCHIMICA ACTA, 2009, 166 (1-2) : 139 - 144
[27] MONO-ETHANOLAMINE, DI-ETHANOLAMINE AND TRI-ETHANOLAMINE DERIVATIVES OF ANTIMONY (III) AND URANIUM (V)
KUMAR, K
DUBEY, S
MISRA, SN
KAPOOR, RN
EGYPTIAN JOURNAL OF CHEMISTRY, 1972, 15 (03): : 267 - 268
[28] SYNTHESES OF ANTIMONY(V) DERIVATIVES FROM TRIMETHYL AND TRIPHENYLANTIMONY(III), DIHYDRIC PHENOLS, AND TERT-BUTYL HYDROPEROXIDE
DODONOV, VA
FEDOROV, AY
USYATINSKY, RI
ZABURDYAEVA, SN
GUSHCHIN, AV
RUSSIAN CHEMICAL BULLETIN, 1995, 44 (04) : 730 - 733
[29] CHARACTERISTICS OF THE (III) SURFACES OF THE III-V INTERMETALLIC COMPOUNDS .3. THE EFFECTS OF SURFACE ACTIVE AGENTS ON INSB AND THE IDENTIFICATION OF ANTIMONY EDGE DISLOCATIONS
LAVINE, MC
GATOS, HC
FINN, MC
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1961, 108 (10) : 974 - 980
[30] Study of homo- and cross-coupling competition in the reaction of triarylbismuth(V) dicarboxylates with methyl acrylate in the presence of a palladium catalyst
Moiseev, DV
Malysheva, YB
Shavyrin, AS
Kurskii, YA
Gushchin, AV
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (16) : 3652 - 3663

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