Co(II), Ni(II), Cu(I) and Pd(II) complexes of p-anisaldene-thiosemicarbazone

被引：0

作者：

Borgh, Geetika ^{[1
]}

Baruah, Jayantajit ^{[1
]}

Kardong, Devid ^{[2
]}

机构：

[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India

[2] Dibrugarh Univ, Dept Life Sci, Dibrugarh 786004, Assam, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2014年 / 53卷 / 12期

关键词：

Coordination chemistry; Antibacterial activity; Antifungal activity; Anticancer activity; Anisaldene; Thiosemicarbazone; Cobalt; Nickel; Copper; Palladium; METAL-COMPLEXES; ANTIBACTERIAL; DERIVATIVES; COPPER(II); NICKEL(II); ANTICANCER; ZINC(II); MN(II); COBALT; ASSAY;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of anisaldene-thiosemicarbazone (HL) with MCl2 center dot 6H(2)O (where M = Co(II) and Ni(II)), Cu(CH3COO)(2)center dot H2O and [Pd(COD)Cl-2] on stirring/refluxing affords six-coordinated [Co(L)(2)(HL)] (1) and four-coordinated [Ni(L)(2)] (2), [Cu(L)(HL)] (3) and [Pd(L)(COD)]Cl (4) complexes. All the complexes have been characterized by conductivity measurements, FTIR, UV-vis, ESI(+) mass, C-13 and H-1 NMR spectroscopy, TGA-DTA analysis, magnetic and cyclic voltammetry studies and screened in vitro for antimicrobial activity by the agar well method. The ligand and the Cu(I) complex have been tested for anticancer activity The Cu(I) complex exhibits quite good antifungal activity against R. solani and F. oxosporum ciceri, and also possesses better antiproliferative activity than the ligand against the cancer cells.

引用

页码：1520 / 1525

页数：6

共 50 条

[31] COMPLEXES OF CU(II), NI(II) AND CO(II) WITH ISOPHTHALIC DIHYDRAZIDE
KUMBHAR, CG
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1982, 91 (01): : 1 - 6
[32] CO(II), NI(II) AND CU(II) COMPLEXES OF DOPAMINE AND ISOPRENALINE
VIJAYVARGIYA, BL
CHAKRAWARTI, PB
SHARMA, HN
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1980, 57 (05) : 471 - 474
[33] COMPLEXES OF CU(II), NI(II) AND CO(II) WITH PYRROLIDINETHIOTRIONE AND PYRROLIDINETRIONE
ZANKOWSKAJASINSKA, W
EILMES, J
ZALESKA, B
ROCZNIKI CHEMII, 1977, 51 (09): : 1617 - 1624
[34] COMPLEXES OF CU(II), NI(II) AND CO(II) WITH SULFAMERAZINE SALICYLALDIMINE
JAIN, P
CHATURVEDI, KK
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (05): : 901 - 903
[35] Spectroscopic and biological approach of Ni(II), Cu(II) and Co(II) complexes of 4-methoxy/ethoxybenzaldehyde thiosemicarbazone glyoxime
Babahan, Ilknur
Eyduran, Fatih
Coban, Esin Poyrazoglu
Orhan, Nil
Kazar, Didem
Biyik, Halil
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 121 : 205 - 215
[36] SULFUR CHELATES 29. NI(II), PD(II), PT(II), CO(III) AND CU(I,II) COMPLEXES OF O-PHENYLDITHIOCARBONATES
FACKLER, JP
SCHUSSLER, DP
CHEN, HW
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1978, 8 (01): : 27 - 42
[37] Co(II), Ni(II) and Cu(II) complexes with phenylthiazole and thiosemicarbazone-derived ligands: synthesis, structure and cytotoxic effects
Sobiesiak, Marta
Muziol, Tadeusz
Rozalski, Marek
Krajewska, Urszula
Budzisz, Elzbieta
NEW JOURNAL OF CHEMISTRY, 2014, 38 (11) : 5349 - 5361
[38] FORMATION-CONSTANTS OF MN(II), CU(II), CO(II), ZN(II), FE(II), NI(II) AND PD(II) COMPLEXES OF PEONOLPHENYLHYDRAZONE
NAIDU, GS
NAIDU, RR
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1991, 30 (04): : 363 - 368
[39] HYDROLYSIS OF PHOSPHODIESTERS WITH NI(II), CU(II), ZN(II), PD(II), AND PT(II) COMPLEXES
DEROSCH, MA
TROGLER, WC
INORGANIC CHEMISTRY, 1990, 29 (13) : 2409 - 2416
[40] INTERMOLECULAR INTERACTIONS AND ISOSTRUCTURALITY IN THE SERIES OF VOLATILE Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) COMPLEXES WITH β-KETOIMINES
Baidina, I. A.
Pervukhina, N. V.
Gromilov, S. A.
JOURNAL OF STRUCTURAL CHEMISTRY, 2024, 65 (10) : 1961 - 1981

← 1 2 3 4 5 →