Synthesis and crystal structure of N,N-dimethylbiguanidinium hexafluorosilicate

被引：2
|
作者：
Gel'mboldt, V. O. [1 ,2 ]
Minacheva, L. Kh. [3 ]
Ganin, E. V. [4 ,5 ]
Sergienko, V. S. [3 ]
Botoshanskii, M. M. [6 ]
机构：
[1] Minist Educ & Sci, Physicochem Inst Human & Environm Protect, UA-65026 Odessa, Ukraine
[2] Natl Acad Sci Ukraine, UA-65026 Odessa, Ukraine
[3] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 1129991, Russia
[4] Odessa State Environm Univ, Minist Educ & Sci, UA-65016 Odessa, Ukraine
[5] Natl Acad Sci Ukraine, UA-65016 Odessa, Ukraine
[6] Technion Israel Inst Technol, IL-32000 Technion, Haifa, Israel
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 54卷 / 12期
关键词：
SYSTEM;
D O I：
10.1134/S0036023609120080
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The complex [(CH3)(2)NC(NH2)NHC(NH2)NH2]SiF6 (I) was synthesized and its structure was determined by X-ray crystallography. The crystals are monoclinic: a = 7.4346(10) , b = 12.7628(10) , c = 11.0828(10) , beta 104.080(10)A degrees, V = 1020.01(18) (3), rho(calc) = 1.780 g/cm(3), mu(MoK (alpha)) = 0.302 mm(-1), Z = 4, space group P2(1)/c. The crystals of I are composed of SiF (6) (2-) anions (Si-F, 1.657(2)-1.699(2) ) and N,N-dimethylbiguanidinium (H2L2+) cations combined in a framework by interionic H-bonds NH center dot center dot center dot F. In the cations, protonation sites are the terminal imide groups.
引用
收藏
页码：1891 / 1894
页数：4
相关论文
共 50 条
  • [41] Compound with possible N → N coordination bond: Synthesis, crystal structure and electronic structure analysis
    Singh, Tejender
    Sahoo, Subash C.
    V. Bharatam, Prasad
    TETRAHEDRON LETTERS, 2021, 77
  • [42] Synthesis and crystal structure of N,N′-bis(4-chlorophenyl)thiourea N,N-dimethylformamide
    Odularu, Ayodele T.
    Ajibade, Peter A.
    Oyedeji, Opeoluwa O.
    Mbese, Johannes Z.
    Puschmann, Horst
    OPEN CHEMISTRY, 2021, 19 (01): : 511 - 517
  • [43] Synthesis and Crystal Structure of N-Ferrocenesulfonyl Hexahydropyridine
    姜林
    贾立生
    李长城
    王立增
    Chinese Journal of Structural Chemistry, 2006, (03) : 257 - 260
  • [44] Crystal structure of borated N,N,N',N'tetramethyldiaminomethane
    Louven, Kathrin
    Quentin, Georgina
    Strohmann, Carsten
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O743 - U347
  • [45] Synthesis and crystal structure of N-ferrocenesulfonyl hexahydropyridine
    Jiang, L
    Jia, LS
    Li, CC
    Wang, LZ
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (03) : 257 - 260
  • [46] SYNTHESIS, CRYSTAL STRUCTURE, AND CONFORMATION OF N-ISONICOTINOYLPHTHALIMIDE
    Turdybekov, K. M.
    Nurkenov, O. A.
    Fazylov, S. D.
    Makhmutova, A. S.
    Turdybekov, D. M.
    Seilkhanov, T. M.
    Arinova, A. E.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (08) : 1279 - 1284
  • [47] Synthesis and Crystal Structure of N-Ferrocenesulfonyl Hexahydropyridine
    姜林
    贾立生
    李长城
    王立增
    结构化学, 2006, (03) : 257 - 260
  • [48] Synthesis and Crystal Structure of Nb0.84N
    Frenzel, Nancy
    Irran, Elisabeth
    Lerch, Martin
    Buchsteiner, Alexandra
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2011, 66 (01): : 1 - 6
  • [49] SYNTHESIS, CRYSTAL STRUCTURE, AND CONFORMATION OF N-ISONICOTINOYLPHTHALIMIDE
    K. M. Turdybekov
    O. A. Nurkenov
    S. D. Fazylov
    A. S. Makhmutova
    D. M. Turdybekov
    T. M. Seilkhanov
    A. E. Arinova
    Journal of Structural Chemistry, 2021, 62 : 1279 - 1284
  • [50] Synthesis and crystal structure of Nb0.84N
    Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany
    不详
    Z. Naturforsch. Sect. B J. Chem. Sci., 1 (1-6):
12345