Magnetic Properties of Manganese-Iron Multi-Metal Cyanide Compound Ni1.15Mn0.35[Fe(CN)6]•6H2O

被引：0
|
作者：
He, Yun [1 ]
Ji, Zhimin [1 ]
Lin, Qing [1 ,2 ]
Huang, Haifu [1 ,3 ]
Kong, Wenjie [1 ]
机构：
[1] Guangxi Normal Univ, Coll Phys & Technol, Guilin 541004, Peoples R China
[2] Hainan Med Coll, Dept Informat Technol, Haikou 571101, Peoples R China
[3] Nanjing Univ, Dept Phys, Nanjing 210093, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2014年 / 26卷 / 17期
基金：
中国国家自然科学基金;
关键词：
Prussian blue analogue; Magnetic transition; Infrared spectroscopy; Ferromagnetic; Spin-glass; PRUSSIAN BLUE ANALOGS; TEMPERATURE;
D O I：
10.14233/ajchem.2014.18136
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A multi-metal prussian blue compound Ni1.15Mn0.35[Fe(CN)(6)]center dot 6H(2)O has been synthesized. The IR spectrum of the compound shows two bands at 2096.42 and 2162.13 cm -1 indicating the existence of two types of cyanide groups. It undergoes a paramagnetic to ferromagnetic transition at 21 K. These results indicate that there exist a ferromagnetic exchange interaction in the complexes. According to Curie-Weiss law, paramagnetic Curie temperature (Q) is 13.81 K and the Curie-Weiss constant (C) is 2.21 cm 3 K mol -1. In addition, the chi' (T) and chi'' (T) show clear peak around 18-20 K. The behaviour of chi' and chi'' is typical of a spin glass state go through a maximum with strong frequency dependence. The observed value of coercive field (H-c) and remanent magnetization (Mr) for the compound are 1.72 KOe and 0.682 mu b, respectively.
引用
收藏
页码：5473 / 5477
页数：5
相关论文
共 50 条
  • [31] MAGNETIC-PROPERTIES OF K5[(H2O)3(SO4)6FE3O].6H2O, A SULFATE ANALOG OF THE TRIMERIC BASIC IRON(III) CARBOXYLATES
    THICH, JA
    TOBY, BH
    POWERS, DA
    POTENZA, JA
    SCHUGAR, HJ
    INORGANIC CHEMISTRY, 1981, 20 (10) : 3314 - 3317
  • [32] Variation of magnetic properties with different annealed temperatures in the Ni3[Fe(CN)6]2•XH2O
    Liu, M.
    Bian, X. F.
    Xia, Y. F.
    Bao, Z.
    Wu, H. S.
    Xu, M. X.
    CURRENT APPLIED PHYSICS, 2011, 11 (03) : 271 - 275
  • [33] A novel cyano-bridged pentanuclear complex:: [{Mn3(MAC)3(H2O)2}Fe(CN)6}2]•6H2O•2CH3OH -: synthesis, crystal structure and, magnetic properties (MAC=pentaaza macrocyclic ligand)
    Tanase, S
    Andruh, M
    Stanica, N
    Mathonière, C
    Rombaut, G
    Golhen, S
    Ouahab, L
    POLYHEDRON, 2003, 22 (10) : 1315 - 1320
  • [34] Synthesis and crystal structure of a novel metal cyanide halide complex (NH4)6Fe(CN)6Cl2.0.4H2O
    Zhang, Li
    Qiao, Xianji
    INORGANICA CHIMICA ACTA, 2025, 576
  • [35] Magnetic Property Study on multi-metal compounds [MA(en)x]y[Fe(CN)6]z•nH2O(MA=Co2+, Gu2+)
    Lin, Qing
    He, Yun
    Xu, Jianmei
    Huang, Haifu
    Wang, Ruijun
    FRONTIERS OF MECHANICAL ENGINEERING AND MATERIALS ENGINEERING, PTS 1 AND 2, 2012, 184-185 : 1050 - +
  • [36] STRUCTURAL AND MAGNETIC-PROPERTIES OF TRANSITION-METAL ARSENATES, AAS(2)O(6), A=MN, CO, AND NI
    NAKUA, AM
    GREEDAN, JE
    JOURNAL OF SOLID STATE CHEMISTRY, 1995, 118 (02) : 402 - 411
  • [37] Magnetic characterization, electronic structure and vibrational properties of (NH4)2 M(SO4)2•6H2O (M=Mn, Ni) crystals
    Pacheco, Tiago S.
    Ludwis, Zelia M. C.
    Ullah, Saif
    de Mendonca, Joao P. A.
    Sato, Fernando
    de Souza, Rafael L.
    Paiva, Edinei C.
    Martins, Maximiliano D.
    Marques, Flavia C.
    Andrade, Gustavo F. S.
    Ghosh, Santunu
    SOLID STATE COMMUNICATIONS, 2021, 334
  • [38] Synthesis and characterization of a new molecular magnet, [Ni(ampy)2]3[Fe(CN)6]2•6H2O, and synthesis, crystal structure and magnetic properties of its mononuclear precursor, trans-[Ni(ampy)2(NO3)2] (ampy=2-aminomethylpyridine)
    Tanase, S
    Ferbinteanu, M
    Andruh, M
    Mathonière, C
    Strenger, I
    Rombaut, G
    POLYHEDRON, 2000, 19 (16-17) : 1967 - 1973
  • [39] Structure, ferromagnetic ordering, anisotropy, and spin reorientation for the two-dimensional cyano-bridged bimetallic compound K2Mn3(H2O)6[Mo(CN)7]2•6H2O
    Larionova, J
    Kahn, O
    Gohlen, S
    Ouahab, L
    Clérac, R
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) : 3349 - 3356
  • [40] Crystal structure and magnetic properties of heterotrinuclear complex (Cutren)(2)Fe(CN)(6).12H(2)O.
    Zou, JZ
    Xu, Z
    Huang, XY
    Zhang, WL
    Shen, XP
    Yu, YP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 101 - INOR
12345