Superconductivity was achieved above 10 K in heavily boron-doped diamond thin films deposited by the microwave plasma-assisted chemical vapor deposition (CVD) method. Advantages of the CVD method are the controllability of boron concentration in a wide range, and a high boron concentration, compared to those obtained using the high-pressure high-temperature method. The superconducting transition temperatures of homoepitaxial (111) films are determined to be 11.4 K for Tc onset and 8.4 K for zero resistance from transport measurements. In contrast, the superconducting transition temperatures of (100) films T-C onset=6.3 K and T-C zero=3.2 K were significantly suppressed. (C) 2007 Elsevier B.V. All rights reserved.
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Univ Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
CNR, Sez Messina, Ist Proc Chimicofis, I-98153 Messina, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Donato, M. G.
Faggio, G.
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Univ Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Faggio, G.
Messina, G.
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Univ Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Messina, G.
Santangelo, S.
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Univ Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Santangelo, S.
Marinelli, Marco
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Univ Roma Tor Vergata, Dipartimento Ingn Meccan, I-00133 Rome, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Marinelli, Marco
Milani, E.
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Univ Roma Tor Vergata, Dipartimento Ingn Meccan, I-00133 Rome, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Milani, E.
Scoccia, M.
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Univ Roma Tor Vergata, Dipartimento Ingn Meccan, I-00133 Rome, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Scoccia, M.
Rinati, G. Verona
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Univ Roma Tor Vergata, Dipartimento Ingn Meccan, I-00133 Rome, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Rinati, G. Verona
Chiorboli, M.
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Univ Catania, Ist Nazl Fis Nucl, Dipartimento Fis & Astron, I-95124 Catania, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Chiorboli, M.
Potenza, R.
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Univ Catania, Ist Nazl Fis Nucl, Dipartimento Fis & Astron, I-95124 Catania, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy
Potenza, R.
Tuve, C.
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Univ Catania, Ist Nazl Fis Nucl, Dipartimento Fis & Astron, I-95124 Catania, ItalyUniv Reggio Calabria, Fac Ingn, Dipartimento Meccan & Mat, I-89060 Reggio Di Calabria, Italy