Fluorinated microporous organic polymers: design and applications in CO2 adsorption and conversion

被引：100
|
作者：
Yang, Zhen-Zhen [1 ]
Zhao, Yanfei [1 ]
Zhang, Hongye [1 ]
Yu, Bo [1 ]
Ma, Zhishuang [1 ]
Ji, Guipeng [1 ]
Liu, Zhimin [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 90期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE CAPTURE; GAS-STORAGE; LINKED POLYMERS; PHENANTHROLINE; COMPLEXES;
D O I：
10.1039/c4cc06423b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form alpha-alkylidene cyclic carbonates at 25 degrees C.
引用
收藏
页码：13910 / 13913
页数：4
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