Tetra-μ-acetato-κ8O:O′-bis[(3-hydroxypyridine-κN)copper(II)]

被引：3

作者：

Gao, S ^{[1
]}

Zhang, XF ^{[1
]}

Huo, LH ^{[1
]}

Zhao, H ^{[1
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷

关键词：

D O I：

10.1107/S1600536804021993

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title dimeric complex, [Cu-2(Ac)(4)(3-PyOH)(2)] or [Cu-2(C2H3O2)(4)(C5H5NO)(2)] (Ac- is acetate and PyOH is hydroxypyridine), each Cu-II atom exists in a square pyramidal coordination environment, defined by four different acetate O atoms and one 3-hydroxypyridine N atom. Two CuII atoms are bridged by four acetate groups, and the center of the dimer corresponds to a crystallographic center of symmetry, the Cu...Cu separation being 2.6598 (8) Angstrom. These dimeric units are linked via O-H...O hydrogen bonds into a two-dimensional layer supramolecular network.

引用

页码：M1405 / M1407

页数：3

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