Crystalline Micelles of Block Copolymers

被引：17
|
作者：
Yang Jiexin [1 ]
Liu Lei [1 ]
Xu Junting [1 ]
机构：
[1] Zhejiang Univ, Dept Polymer Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
来源：
PROGRESS IN CHEMISTRY | 2014年 / 26卷 / 11期
基金：
中国国家自然科学基金;
关键词：
block copolymer; crystallization; self-assembly; micelle; CORE-FORMING METALLOBLOCK; CONJUGATED POLYTHIOPHENE CORE; COIL DIBLOCK COPOLYMER; TO-ROD TRANSITION; CYLINDRICAL MICELLES; TRIBLOCK COPOLYMERS; AQUEOUS-SOLUTION; POLYETHYLENE-B-POLY(ETHYLENE OXIDE); MORPHOLOGICAL TRANSFORMATION; POLYETHYLENE CORES;
D O I：
10.7536/PC140703
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Recently the crystallization-driven self-assembly of block copolymers into semicrystalline micelles in the selective solvent has been paid increasing attention due to the good controllability. In this paper we first review some factors controlling the morphology and size of the semicrystalline micelles of block copolymers, including solvent quality, structure of block copolymers, and crystallization temperature. The living growth of semicrystalline micelles with time and formation of "block co-micelles" using micelles as building blocks are also introduced. Finally, currently existing problems and outlook in this field are discussed.
引用
收藏
页码：1811 / 1820
页数：10
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