Studies on synthesis of water-soluble polymer-supported transition metal polypyridyl complexes and their interaction with DNA

被引：1
|
作者：
Wang, YP [1 ]
Zhang, FA [1 ]
Zhang, HT [1 ]
Li, YF [1 ]
机构：
[1] NW Normal Univ, Inst Polymer, Lanzhou 730070, Peoples R China
来源：
JOURNAL OF BIOACTIVE AND COMPATIBLE POLYMERS | 2004年 / 19卷 / 06期
关键词：
transition metal polypyridyl complexes; polymer synthesis; DNA; interaction;
D O I：
10.1177/0883911504048326
中图分类号：
Q81 [生物工程学（生物技术）]; Q93 [微生物学];
学科分类号：
071005 ; 0836 ; 090102 ; 100705 ;
摘要：
Five water-soluble polymer-supported transition metal polypyridyl complexes were synthesized from poly(acrylic acid-co-N-vinyl pyrrolidone) with 2-methyl-3-hydroxyl benzaldehyde, o-phenanthroline and metal acetate salts. Infrared spectra (IR), thermo-gravimetric and differential thermal analysis (TG-DTA), Inductance Coupling Plasma (ICP) and X-ray photoelectron spectroscopy (XPS) were used to characterize these composites and structures. The interaction with DNA was studied by the fluorescent probe and gel electrophoresis methods. The results indicated that these complexes had strong interactions with DNA.
引用
收藏
页码：481 / 490
页数：10
相关论文
共 50 条
  • [1] Studies on the interaction of DNA and water-soluble polymer-supported Schiff base complex
    Wang, YP
    Xiao, YN
    Zhang, CX
    Wang, RM
    JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2001, 38 (11): : 1099 - 1104
  • [2] Studies on the interaction of water-soluble polymer-supported ferrocenyl Schiff base with DNA
    Liu, L
    Zhang, HT
    Wang, YP
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2003, 23 (06) : 570 - 573
  • [3] The synthesis of water-soluble asymmetric porphyrins, their metal complexes and their interaction with CT DNA
    Han, GY
    Yang, P
    ACTA CHIMICA SINICA, 2001, 59 (06) : 925 - 930
  • [4] Synthesis and structural studies of polymer-supported transition metal complexes: Efficient catalysts for oxidation of phenol
    Nath, N.
    Routaray, A.
    Das, Y.
    Maharana, T.
    Sutar, A. K.
    KINETICS AND CATALYSIS, 2015, 56 (06) : 718 - 732
  • [5] Synthesis and structural studies of polymer-supported transition metal complexes: Efficient catalysts for oxidation of phenol
    N. Nath
    A. Routaray
    Y. Das
    T. Maharana
    A. K. Sutar
    Kinetics and Catalysis, 2015, 56 : 718 - 732
  • [6] Syntheses of water-soluble polymer-supported ferrocenyl Schiff bases
    Liu, L
    Zhang, HT
    Wang, YP
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2002, 22 (04) : 286 - 288
  • [7] Synthesis and Application of Water-Soluble NHC Transition-Metal Complexes
    Schaper, Lars-Arne
    Hock, Sebastian J.
    Herrmann, Wolfgang A.
    Kuehn, Fritz E.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (01) : 270 - 289
  • [8] Soluble polymer-supported organic synthesis
    Toy, PH
    Tanda, KD
    ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (08) : 546 - 554
  • [9] Soluble polymer-supported synthesis of arylpiperazines
    Pan, PC
    Sun, CM
    TETRAHEDRON LETTERS, 1998, 39 (51) : 9505 - 9508
  • [10] Soluble polymer-supported synthesis of isoxazoles
    Shang, YJ
    Wang, YG
    TETRAHEDRON LETTERS, 2002, 43 (12) : 2247 - 2249
12345