Development of catalysts for natural gas reforming: Nickel-magnesia solid solution catalyst

被引:16
|
作者
Fujimoto, K [1 ]
Tomishige, K [1 ]
Yamazaki, O [1 ]
Chen, YG [1 ]
Li, XH [1 ]
机构
[1] Univ Tokyo, Grad Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 113, Japan
关键词
D O I
10.1163/156856798X00230
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nickel-magnesia solid solution catalyst (Ni0.03Mg0.97O) was found to have high resistance to carbon formation during CO2 reforming of methane. Although deactivation due to the oxidation of reduced Ni happened, it is easily prevented by the addition of hydrogen to the reaction gas. The amount of deposited carbon increased gradually with increase in the reaction pressure. It was also found that the addition of calcium is very effective to its inhibition.
引用
收藏
页码:259 / 271
页数:13
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