A calorimetric study of propylene carbonate plus acetic or propionic acid at (288.15, 298.15 and 313.15)K

被引：7
|
作者：
Comelli, F
Righetti, MC
Francesconi, R
机构：
[1] CNR, Ctr Studio Fis Macromol, I-40126 Bologna, Italy
[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
来源：
THERMOCHIMICA ACTA | 1997年 / 306卷 / 1-2期
关键词：
calorimeter; enthalpies; extended cell model; heat capacity;
D O I：
10.1016/S0040-6031(97)00289-X
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Determinations of heat capacities, C-p, and excess molar enthalpies, H-m(E), of the binary mixtures propylene carbonate + acetic or propionic acid were carried out at (285.15, 298.15 and 313.15)K using a Perkin-Elmer DSC differential scanning calorimeter and an LKB flow microcalorimeter. All experimental values are positive and increase with the increase of temperature. The data have been fitted to a simple cubic polynomial (for C-p) and the Redlich-Kister equation (for H-m(E)) to estimate the adjustable parameters and standard deviations of these systems. Results have been discussed in terms of molecular interactions and have been interpreted by an extended cell model. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：37 / 43
页数：7
相关论文
共 50 条
  • [21] Excess molar volumes, viscosities, and refractive indices of tetraethylene glycol dimethyl ether plus dimethyl carbonate, plus diethyl carbonate, and plus propylene carbonate at 298.15 K
    Pal, A
    Dass, G
    Kumar, A
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (01): : 2 - 5
  • [22] Viscosities of the ternary mixture (cyclohexane plus tetrahydrofuran plus chlorocyclohexane) at 298.15 and 313.15 K
    Gascón, I
    Lafuente, C
    Cea, P
    Royo, FM
    Urieta, JS
    FLUID PHASE EQUILIBRIA, 1999, 164 (01) : 143 - 155
  • [23] Excess molar enthalpies and excess molar volumes of dialkyl carbonates + acetic or propionic acid at 298.15 K
    Universita' degli Studi, Bologna, Italy
    J Chem Eng Data, 4 (702-704):
  • [24] Chemical equilibrium for the reactive system propionic acid plus ethanol plus ethyl propionate + water at 303.15 and 313.15 K
    Toikka, Maria
    Sadaeva, Anna
    Samarov, Artemiy
    Golikova, Alexandra
    Trofimova, Maya
    Shcherbakova, Nataliya
    Toikka, Alexander
    FLUID PHASE EQUILIBRIA, 2017, 451 : 91 - 95
  • [25] Diffusion coefficient of 10-methylphenothiazine and dimethyl carbonate mixture from 288.15 K to 313.15 K
    Zhang, Ying
    Zhang, Shi
    Peng, Sanguo
    He, Maogang
    THERMOCHIMICA ACTA, 2017, 656 : 32 - 37
  • [26] Excess molar enthalpies of binary mixtures containing propylene carbonate plus 23 alkanoates at 298.15 K
    Comelli, F
    Francesconi, R
    Ottani, S
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (03): : 333 - 336
  • [27] Speeds of sound and isentropic compressibilities of mixtures containing some polyethers plus propylene carbonate at 298.15 K
    Pal, A
    Kumar, A
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 1999, 37 (11) : 810 - 817
  • [28] DENSITIES AND EXCESS MOLAR VOLUMES OF PROPYLENE CARBONATE PLUS LINEAR AND CYCLIC-KETONES AT 298.15 K
    COMELLI, F
    FRANCESCONI, R
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (04): : 808 - 810
  • [29] Densities and viscosities of propylene carbonate with aromatic hydrocarbons (benzene, 1,4-dimethylbenzene and ethylbenzene) at 288.15, 298.15 and 308.15K
    Wankhede, Dnyaneshwar
    Wankhede, Nilesh
    Lande, Machhindra
    Arbad, Balasaheb
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2008, 46 (03) : 319 - 327
  • [30] (Liquid plus liquid) equilibria of the (water plus propionic acid plus Aliquat 336 plus organic solvents) at T=298.15 K
    Uslu, Hasan
    Inci, Ismail
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2007, 39 (05): : 804 - 809
12345