Preparation of benzolactams by Pd(OAc)2-catalyzed direct aromatic carbonylation

被引：272

作者：

Orito, K ^{[1
]}

Horibata, A ^{[1
]}

Nakamura, T ^{[1
]}

Ushito, H ^{[1
]}

Nagasaki, H ^{[1
]}

Yuguchi, M ^{[1
]}

Yamashita, S ^{[1
]}

Tokuda, M ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Mol Chem, Organ Synth Lab, Sapporo, Hokkaido 0608628, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 44期

关键词：

D O I：

10.1021/ja045342+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We developed a new method for Pd(II)-catalyzed direct aromatic carbonylation in a phosphine-free catalytic system using Pd(OAc)2 and Cu(OAc)2 in an atmosphere of CO gas containing air. The carbonylation proceeded with ortho-palladation, inducing a remarkable site selectivity to afford a variety of five- or six-membered benzolactams from secondary ω-arylalkylamines, such as N-alkylbenzylamines or N-alkylphenethylamines. Copyright © 2004 American Chemical Society.

引用

页码：14342 / 14343

页数：2

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