Butenyl-substituted alkaline-earth metallocenes: A first step towards olefin complexes of the alkaline-earth metals

被引：46
|
作者：
Schumann, H
Schutte, S
Kroth, HJ
Lentz, D
机构：
[1] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
[2] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期
关键词：
alkaline-earth metals; metallocenes; olefin complexes;
D O I：
10.1002/anie.200460927
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Sandwich any one? The bis(butenyltetramethylcyclopentadienyl) complexes of calcium (2), strontium and barium exhibit an interaction of the alkaline-earth metals with olefin double bonds. Whereas the magnesium derivative (1) crystallizes as a sandwich complex with coplanar cyclopentadienyl ligands and free butenyl side chains, these coordinate to the metal in the analogous but open sandwich complexes of the larger metals calcium, strontium, and barium.
引用
收藏
页码：6208 / 6211
页数：4
相关论文
共 50 条
  • [21] Alkaline-earth metal complexes with pivaloylacetone
    Kuz'mina, NP
    Eliseeva, SV
    Chugarov, NV
    Martynenko, LI
    Min, YS
    Kim, DS
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2002, 28 (09) : 603 - 607
  • [22] Alkaline-earth metal complexes with pivaloylacetone
    Kuz'mina N.P.
    Eliseeva S.V.
    Chugarov N.V.
    Martynenko L.I.
    Min Y.-S.
    Kim D.-S.
    Russian Journal of Coordination Chemistry, 2002, 28 (9) : 603 - 607
  • [23] STABILITY OF ALKALINE-EARTH CITRATE COMPLEXES
    RUMBAUT, NA
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1971, 80 (1-2): : 63 - &
  • [24] NON-STOICHIOMETRY IN ALKALINE-EARTH EXCESS ALKALINE-EARTH TITANATES
    UDAYAKUMAR, KR
    CORMACK, AN
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1989, 50 (01) : 55 - 60
  • [25] ALPHA-PICOLINE COMPLEXES OF THIOCYANATES OF ALKALINE-EARTH METALS
    BHATTACHARYA, GC
    DASGUPTA, HC
    INDIAN JOURNAL OF CHEMISTRY, 1963, 1 (04): : 152 - &
  • [26] ALKALINE-EARTH CHLOROSULFATES
    MAIRESSE, G
    BARBIER, P
    HEUBEL, J
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE I-PHYSICOCHIMIE DES SYSTEMES LIQUIDES ELECTROCHIMIE CATALYSE GENIE CHIMIQUE, 1974, (7-8): : 1297 - 1301
  • [27] ALKALINE-EARTH SCANDATES
    KWESTROO, W
    LANGEREIS, C
    NABBEN, H
    MATERIALS RESEARCH BULLETIN, 1982, 17 (05) : 641 - 646
  • [28] Alkaline-earth arsenuirets
    Lebeau, P
    ANNALES DE CHIMIE ET DE PHYSIQUE, 1902, 25 : 470 - 483
  • [29] On alkaline-earth acetates
    Colson, A
    COMPTES RENDUS HEBDOMADAIRES DES SEANCES DE L ACADEMIE DES SCIENCES, 1903, 137 : 1061 - 1063
  • [30] Electrophysical properties of titanates of alkaline-earth metals
    L. A. Dunyushkina
    Russian Journal of Electrochemistry, 2007, 43 : 894 - 900
12345