Coordination and Redox Non-innocent Behavior of Hybrid Ligands Containing Tellurium

被引：35

作者：

Jones, J. Stuart ^{[1
]}

Gabbai, Francois P. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

CHEMISTRY LETTERS | 2016年 / 45卷 / 04期

基金：

美国国家科学基金会;

关键词：

Coordination chemistry; Organotellurium compound; Redox non-innocent behavior; SIGMA-ACCEPTOR LIGANDS; PHOTOREDUCTIVE ELIMINATION; MOLECULAR-STRUCTURE; HYDROGEN-PRODUCTION; STRUCTURAL-CHARACTERIZATION; ORGANOTELLURIUM HALIDES; CATALYTIC APPLICATIONS; PALLADIUM COMPLEXES; GOLD(I) COMPLEX; BOND-ACTIVATION;

D O I：

10.1246/cl.160103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Despite the well-studied redox and Lewis acidic attributes of organotellurium compounds, such properties are underutilized in their coordination chemistry. This review aims to highlight recent developments in the coordination chemistry of tellurium ligands supported by auxiliary donor groups, which facilitate both coordination and redox non-innocent behavior at the tellurium center by enforcing the Te-M interaction.

引用

页码：376 / 384

页数：9

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