Metallophilic interactions in iodido(2,2′:6′,2"-terpyridine)-platinum(II) diiodidoaurate(I)

被引：11
|
作者：
Angle, Christina S.
Woolard, Kathryn J.
Kahn, Michael I.
Golen, James A.
Rheingold, Arnold L.
Doerrer, Linda H.
机构：
[1] Boston Univ, Dept Chem, Boston, MA 02215 USA
[2] Columbia Univ Barnard Coll, Dept Chem, New York, NY 10027 USA
[3] Univ Massachusetts, Dept Chem & Biochem, N Dartmouth, MA 02747 USA
[4] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
[5] Columbia Univ, Nanoscale Sci & Engn Ctr, Schapiro Ctr CEPSR 1001, New York, NY 10027 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2007年 / 63卷 / m231-m234期
关键词：
D O I：
10.1107/S0108270107015843
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, [PtI(C15H11N3)][AuI2], the [PtI(terpy)](+) cations (terpy is 2,2':6',2 ''-terpyridine) stack in pairs about inversion centers through Pt center dot center dot center dot Pt interactions of 3.5279 (5) angstrom. The [AuI2](-) anions also exhibit pairwise stacking, with Au center dot center dot center dot I distances of 3.7713 (5) angstrom. The [PtI(terpy)](+) cations and [AuI2](-) anions aggregate forming infinite arrays of stacked center dot center dot center dot({[PtI(terpy)](+)center dot center dot center dot[PtI(terpy)](+)}center dot center dot center dot{[AUI(2)](-)center dot center dot center dot[AUI(2)](-)})center dot center dot center dot units.
引用
收藏
页码：M231 / M234
页数：4
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