Fast Li+ ion conduction in Li2O (Al2O3 Ga2O3) TiO2 P2O5 glass ceramics

被引：108
|
作者：
Fu, J [1 ]
机构：
[1] Ohara Inc, Res Inst, Sagamihara, Kanagawa 22911, Japan
来源：
JOURNAL OF MATERIALS SCIENCE | 1998年 / 33卷 / 06期
关键词：
D O I：
10.1023/A:1017559619391
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Fast lithium ionic conducting glass-ceramics have been obtained by heat-treatment of glasses in the systems Li2O-M2O3-TiO2-P2O5 (M = Al and Ga). The glass-ceramics were mainly composed of LiTi2(PO4)(3) in which Ti4+ ions were partially replaced by M3+ ions. Considerable enhancement of the conductivity with the substitution of M3+ ions for Ti4+ ions was observed. The maximum conductivity obtained at room temperature was 1.3 x 10(-3) S cm(-1) for the aluminum system and 9 x 10(-4) S cm(-1) for the gallium system. (C) 1998 Chapman & Hall.
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收藏
页码：1549 / 1553
页数：5
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