Reverse Atom Transfer Radical Polymerization of Acrylonitrile Catalyzed by FeCl3/Lactic Acid

被引：5

作者：

Zong, Guangxi ^{[1
]}

Chen, Hou ^{[1
]}

Wang, Chunhua ^{[1
]}

Liu, Delong ^{[1
]}

Hao, Zhihai ^{[1
]}

机构：

[1] Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Peoples R China

来源：

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY | 2010年 / 47卷 / 08期

关键词：

RATRP; FeCl3; LA; AN; METHYL-METHACRYLATE; ELECTRON-TRANSFER; STYRENE; ATRP; COPOLYMERS; COMPLEXES; LIGANDS; ARRAYS;

D O I：

10.1080/10601325.2010.492186

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Reverse atom transfer radical polymerization (RATRP) of acrylonitrile (AN) was carried out using azobisisobutyronitrile (AIBN) as initiator, ferric trichloride anhydrous (FeCl3)/lactic acid (LA) as catalyst system; a ratio of FeCl3/LA was 1:2 gave the best control. RATRP of AN with N,N-dimethylformamide (DMF) as solvent gave the moderate polymerization rate and the narrowest polydispersity index (PDI). When FeCl3 was replaced by CuBr2, RATRP of AN showed a longer induction period. When Cu was added to the CuBr2-based catalyst system, the induction period was reduced. 1H-NMR spectra of PAN verified the possibility of controlled/living polymerization for future chain extension.

引用

页码：804 / 808

页数：5

共 50 条

[21] Microwave-assisted controlled copolymerization of styrene and acrylonitrile catalyzed by FeCl3/isophthalic acid
Wang, Guoxiang
Wu, Hu
POLYMER BULLETIN, 2011, 67 (09) : 1809 - 1821
[22] Microwave-assisted controlled copolymerization of styrene and acrylonitrile catalyzed by FeCl3/isophthalic acid
Guoxiang Wang
Hu Wu
Polymer Bulletin, 2011, 67 : 1809 - 1821
[23] Atom Transfer Radical Polymerization of Acrylonitrile in Ionic Liquids
张玉梅
张红燕
陈小军
王华平
Journal of Donghua University(English Edition), 2011, 28 (01) : 57 - 61
[24] Synthesis of polyacrylonitrile via reverse atom transfer radical polymerization initiated by 1,1,2,2-tetraphenyl-1,2-ethanediol/FeCl3/triphenylphosphine
Hou, Chen
Ying, Liang
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 104 (06) : 4041 - 4045
[25] Synthesis of polyacrylonitrile via reverse atom transfer radical polymerization (ATRP) initiated by diethyl 2,3-dicyano-2,3-diphenylsuccinate, FeCl3, and triphenylphosphine
Hou, C
Qu, RJ
Ji, CN
Wang, CH
Wang, CG
POLYMER INTERNATIONAL, 2006, 55 (03) : 326 - 329
[26] Reverse atom transfer radical polymerization in miniemulsion
Li, M
Matyjaszewski, K
MACROMOLECULES, 2003, 36 (16) : 6028 - 6035
[27] Atom transfer radical polymerization of styrene with FeCl2/acetic acid as the catalyst system
Zhu, SN
Yan, DY
Zhang, GS
POLYMER BULLETIN, 2001, 45 (06) : 457 - 464
[28] Atom transfer radical polymerization of styrene with FeCl2/acetic acid as the catalyst system
Shenim Zhu
Deyue Yan
Guosheng Zhang
Polymer Bulletin, 2001, 45 : 457 - 464
[29] Reverse Atom Transfer Radical Polymerization of (-)-Menthyl Methacrylate
Yong An XU
Chinese Chemical Letters, 2003, (03) : 245 - 246
[30] Reverse atom transfer radical polymerization of (-)-menthyl methacrylate
Xu, YA
Xue, H
Ding, YJ
Gao, LX
Ding, MX
CHINESE CHEMICAL LETTERS, 2003, 14 (03) : 245 - 246

← 1 2 3 4 5 →