Titanium Nitride-Supported Platinum with Metal-Support Interaction for Boosting Photocatalytic H2 Evolution of Indium Sulfide

被引：49
|
作者：
Liu, Siqi [1 ,2 ]
Qi, Weiliang [1 ,2 ]
Adimi, Samira [1 ,2 ]
Guo, Haichuan [1 ,2 ]
Weng, Bo [3 ]
Attfield, John Paul [4 ,5 ]
Yang, Minghui [1 ,2 ]
机构：
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Peoples R China
[2] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
[3] Katholieke Univ Leuven, cMACS, Dept Microbial & Mol Syst, B-3001 Leuven, Belgium
[4] Univ Edinburgh, Ctr Sci Extreme Condit, Edinburgh EH9 3JJ, Midlothian, Scotland
[5] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
来源：
ACS APPLIED MATERIALS & INTERFACES | 2021年 / 13卷 / 06期
基金：
英国工程与自然科学研究理事会;
关键词：
metal-support interaction; transition metal nitride; platinum; photocatalytic H-2 evolution; core-shell nanostructure; ELECTRONIC-STRUCTURE; HYDROGEN-PRODUCTION; ELECTROCATALYST; EFFICIENT; REDUCTION; SYSTEMS; TIN; NANOPARTICLES; TEMPERATURE; COCATALYST;
D O I：
10.1021/acsami.0c20919
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Metal-support interaction strongly influences the catalytic properties of metal-based catalysts. Here, titanium nitride (TiN) nanospheres are shown to be an outstanding support, for tuning the electronic property of platinum (Pt) nanoparticles and adjusting the morphology of indium sulfide (In2S3) active components, forming flower-like core-shell nanostructures (TiN-Pt@In2S3). The strong metal-support interaction between Pt and TiN through the formation of Pt-Ti bonds favors the migration of charge carriers and leads to the easy reducibility of TiN-Pt, thus improving the photocatalytic atom efficiency of Pt. The TiN-Pt@In2S3 composite shows reduction of Pt loading by 70% compared to the optimal Pt-based system. In addition, the optimal TiN-Pt@In2S3 composite exhibits a H-2 evolution rate 4 times that of a Pt reference. This increase outperforms all other supports reported thus far.
引用
收藏
页码：7238 / 7247
页数：10
相关论文
共 50 条
  • [21] Surface analysis of supported platinum catalysts-encapsulation model for metal-support interaction: An XPS study
    Malathi, R
    Rao, PM
    Viswanathan, B
    Viswanath, RP
    INDIAN JOURNAL OF ENGINEERING AND MATERIALS SCIENCES, 1998, 5 (05) : 285 - 290
  • [22] Electronic metal-support interaction enhanced oxygen reduction activity and stability of boron carbide supported platinum
    Jackson, Colleen
    Smith, Graham T.
    Inwood, David W.
    Leach, Andrew S.
    Whalley, Penny S.
    Callisti, Mauro
    Polcar, Tomas
    Russell, Andrea E.
    Levecque, Pieter
    Kramer, Denis
    NATURE COMMUNICATIONS, 2017, 8
  • [23] MOLECULAR-ORBITAL STUDY OF STRONG METAL-SUPPORT INTERACTION BETWEEN PLATINUM AND TITANIUM-DIOXIDE
    HORSLEY, JA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (11) : 2870 - 2874
  • [24] Electronic metal-support interaction enhanced oxygen reduction activity and stability of boron carbide supported platinum
    Colleen Jackson
    Graham T. Smith
    David W. Inwood
    Andrew S. Leach
    Penny S. Whalley
    Mauro Callisti
    Tomas Polcar
    Andrea E. Russell
    Pieter Levecque
    Denis Kramer
    Nature Communications, 8
  • [25] Boosting photocatalytic H2 evolution by ingenious construction of isotype heptazine/triazine based porous carbon nitride heterojunction
    Chen, Xueru
    Li, Xue
    Wu, Jun
    Fang, Cheng
    Ding, Jing
    Wan, Hui
    Guan, Guofeng
    SEPARATION AND PURIFICATION TECHNOLOGY, 2022, 297
  • [26] Stable Co-Catalyst-Free Photocatalytic H2 Evolution From Oxidized Titanium Nitride Nanopowders
    Zhou, Xuemei
    Zolnhofer, Eva M.
    Nhat Truong Nguyen
    Liu, Ning
    Meyer, Karsten
    Schmuki, Patrik
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (45) : 13385 - 13389
  • [27] Titanium nitride-supported Cu-Ni bifunctional electrocatalysts for CO2 reduction and the oxygen evolution reaction
    Pan, Hanqing
    Barile, Christopher J.
    SUSTAINABLE ENERGY & FUELS, 2020, 4 (11): : 5654 - 5664
  • [28] Increasing the Oxygen-Evolution Reaction Performance of Nanotubular Titanium Oxynitride-Supported Ir Nanoparticles by a Strong Metal-Support Interaction
    Bele, Marjan
    Jovanovic, Primoz
    Marinko, Ziva
    Drev, Sandra
    Selih, Vid Simon
    Kovac, Janez
    Gaberscek, Miran
    Podborsek, Gorazd Koderman
    Drazic, Goran
    Hodnik, Nejc
    Kokalj, Anton
    Suhadolnik, Luka
    ACS CATALYSIS, 2020, 10 (22) : 13688 - 13700
  • [29] H2-Induced Reconstruction of Supported Pt Clusters: Metal-Support Interaction versus Surface Hydride
    Mager-Maury, Christophe
    Bonnard, Gaetan
    Chizallet, Celine
    Sautet, Philippe
    Raybaud, Pascal
    CHEMCATCHEM, 2011, 3 (01) : 200 - 207
  • [30] Promoting H2 Activation over Molybdenum Carbide by Modulation of Metal-Support Interaction for Efficient Catalytic Hydrogenation
    Ma, Ling
    Chen, Ping
    Zhang, Guangji
    Wang, Liqiang
    Tang, Feiying
    Zhao, Xiaojun
    Wang, Jin
    Huang, Jianhan
    Liu, You-Nian
    CHEMCATCHEM, 2021, 13 (14) : 3283 - 3289
12345