Supramolecular AB diblock copolymers

被引:127
|
作者
Yang, XW
Hua, FJ
Yamato, K
Ruckenstein, E
Gong, B [1 ]
Kim, W
Ryu, CY
机构
[1] SUNY Buffalo, Univ Buffalo, Dept Chem, Buffalo, NY 14260 USA
[2] SUNY Buffalo, Univ Buffalo, Dept Chem & Biol Engn, Buffalo, NY 14260 USA
[3] Rensselaer Polytech Inst, Dept Chem & Biol Chem, Troy, NY 12180 USA
关键词
block copolymers; hydrogen bonds; nanostructures; phase transitions; supramolecular chemistry;
D O I
10.1002/anie.200460472
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure presented). Hydrogen-bonded duplexes of incompatible polystyrene and poly(ethylene glycol) chains have been prepared that show microphase separation (see picture). Differential scanning calorimetric studies of the phase transitions for these copolymers show that they behave like typical covalently bonded diblock copolymers at temperatures below 170°C.
引用
收藏
页码:6471 / 6474
页数:4
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