Photocatalytic Activity and Mechanical Properties of Cements Modified with TiO2/N

被引:26
|
作者
Janus, Magdalena [1 ,2 ]
Madraszewski, Szymon [2 ]
Zajac, Kamila [1 ]
Kusiak-Nejman, Ewelina [3 ]
Morawski, Antoni W. [3 ]
Stephan, Dietmar [2 ]
机构
[1] West Pomeranian Univ Technol, Fac Civil Engn & Architecture, Al Piastow 50, PL-70311 Szczecin, Poland
[2] Tech Univ Berlin, Bldg Mat & Construct Chem, Gustav Meyer Allee 25, D-13355 Berlin, Germany
[3] West Pomeranian Univ Technol, Fac Chem Technol & Engn, Ul Pulaskiego 10, PL-70310 Szczecin, Poland
关键词
photoactive cement; TiO2/N; NOx decomposition; mechanical properties; CEMENTITIOUS MATERIALS; BUILDING-MATERIALS; TITANIUM-DIOXIDE; NITROGEN-OXIDES; NOX REMOVAL; NANOPARTICLES; HYDRATION; CONCRETE; MICROSTRUCTURE; NANO-TIO2;
D O I
10.3390/ma12223756
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, studies of the mechanical properties and photocatalytic activity of new photoactive cement mortars are presented. The new building materials were obtained by the addition of 1, 3, and 5 wt % (based on the cement content) of nitrogen-modified titanium dioxide (TiO2/N) to the cement matrix. Photocatalytic active cement mortars were characterized by measuring the flexural and the compressive strength, the hydration heat, the zeta potential of the fresh state, and the initial and final setting time. Their photocatalytic activity was tested during NOx decomposition. The studies showed that TiO2/N gives the photoactivity of cement mortars during air purification with an additional positive effect on the mechanical properties of the hardened mortars. The addition of TiO2/N into the cement shortened the initial and final setting time, which was distinctly observed using 5 wt % of the photocatalyst in the cement matrix.
引用
收藏
页数:12
相关论文
共 50 条
  • [31] Nanostructured TiO2 modified by perfluoropolyethers: Gas phase photocatalytic activity
    Bianchi, Claudia L.
    Ardizzone, Silvia
    Cappelletti, Giuseppe
    Cerrato, Giuseppina
    Navarrini, Walter
    Sansotera, Maurizio
    JOURNAL OF MATERIALS RESEARCH, 2010, 25 (01) : 96 - 103
  • [32] The influence of surface properties on the photocatalytic activity of nanostructured TiO2
    Yeung, KL
    Yau, ST
    Maira, AJ
    Coronado, JM
    Soria, J
    Yue, PL
    JOURNAL OF CATALYSIS, 2003, 219 (01) : 107 - 116
  • [33] Photocatalytic activity of nitrogen-modified TiO2/SiO2
    Isaev, A. B.
    Gasanova, F. G.
    Shabanov, N. S.
    Giraev, K. M.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (10) : 1798 - 1801
  • [34] Structure, surface properties and photocatalytic activity of TiO2 nanoparticles
    Shang, J
    Xu, ZL
    Du, YG
    Li, JM
    JOURNAL OF INORGANIC MATERIALS, 2001, 16 (06) : 1211 - 1216
  • [35] Photocatalytic activity of nitrogen-modified TiO2/SiO2
    A. B. Isaev
    F. G. Gasanova
    N. S. Shabanov
    K. M. Giraev
    Russian Journal of Physical Chemistry A, 2014, 88 : 1798 - 1801
  • [36] Physical and mechanical properties assessment of glass ionomer cements modified with TiO2 and Mg-doped hydroxyapatite nanoparticles
    Ramic, Bojana
    Cvjeticanin, Milica
    Bajkin, Branislav
    Drobac, Milan
    Milanovic, Marija
    Rajnovic, Dragan
    Krstonosic, Veljko
    Veljovic, Dorde
    JOURNAL OF APPLIED BIOMATERIALS & FUNCTIONAL MATERIALS, 2024, 22
  • [37] Fabrication and Photocatalytic Properties of TiO2 Nanotube Arrays Modified with Phosphate
    Nakata, Kazuya
    Liu, Baoshun
    Ishikawa, Yosuke
    Sakai, Munetoshi
    Saito, Hidenori
    Ochiai, Tsuyoshi
    Sakai, Hideki
    Murakami, Taketoshi
    Abe, Masahiko
    Takagi, Katsuhiko
    Fujishima, Akira
    CHEMISTRY LETTERS, 2011, 40 (10) : 1107 - 1109
  • [38] Fabrication and photocatalytic properties of TiO2 nanotube arrays modified by CdS
    Xue, Feng
    Wang, Ling
    Xue, Jianjun
    Bao, Zuguo
    Tao, Haijun
    Cao, Zhibin
    Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering, 2009, 38 (07): : 1238 - 1241
  • [39] Preparation of ZnO modified TiO2 nanoporous coatings and their photocatalytic properties
    Drunka, R.
    Grabis, J.
    Letlena, A.
    Jankovica, Dz
    Krumina, A.
    Steins, I.
    FUNCTIONAL MATERIALS AND NANOTECHNOLOGIES (FM&NT 2018), 2019, 503
  • [40] Fabrication and Photocatalytic Properties of TiO2 Nanotube Arrays Modified by CdS
    Xue Feng
    Wang Ling
    Xue Jianjun
    Bao Zhuguo
    Tao Haijun
    Cao Zhibing
    RARE METAL MATERIALS AND ENGINEERING, 2009, 38 (07) : 1238 - 1241