Reactions of quinones with organometallic compounds: correlation analysis of substituent effects

被引：1
|
作者：
Kurskii, Yu. A. [1 ]
Egorochkin, A. N. [1 ]
Abakumov, G. A. [1 ]
机构：
[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, 49 Ul Tropinina, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2017年 / 66卷 / 03期
关键词：
quinone; organometallic compound; correlation analysis; polarization effect; ELECTRON-TRANSFER; REAGENTS; BENZOQUINONE;
D O I：
10.1007/s11172-017-1762-3
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effects of substituents in lithium, magnesium, zinc, and cadmium organometallic compounds in their reactions with p-benzoquinone and 3,6-di-tert-butyl-o-benzoquinone on the ratio of addition and reduction products were considered. The reduction of quinones follows a homolytic mechanism of single electron transfer. The results of correlation analysis confirmed a suggestion that the addition to quinones followed a nucleophilic (heterolytic) mechanism.
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页码：497 / 501
页数：5
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