Remarkable activity enhancement by trimethylsilylation in oxidation of alkenes and alkanes with H2O2 catalyzed by titanium-containing mesoporous molecular sieves

被引：239
|
作者：
Tatsumi, T [1 ]
Koyano, KA [1 ]
Igarashi, N [1 ]
机构：
[1] Univ Tokyo, Sch Engn, Engn Res Inst, Tokyo 113, Japan
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 03期
关键词：
D O I：
10.1039/a706175g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Titanium-containing mesoporous materials, Ti-MCM-41 and Ti-MCM-48, have been successfully modified by trimethylsilylation to exhibit enhanced catalytic activity in the oxidation of alkenes and alkanes with H2O2.
引用
收藏
页码：325 / 326
页数：2
相关论文
共 50 条
  • [21] Asymmetric oxidation of sulfides with H2O2 catalyzed by titanium complexes with aminoalcohol derived Schiff bases
    Bryliakov, Konstantin P.
    Talsi, EvIrenii P.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 264 (1-2) : 280 - 287
  • [22] A dimeric titanium-containing polyoxometalate.: Synthesis, characterization, and catalysis of H2O2-based thioether oxidation
    Kholdeeva, OA
    Maksimov, GM
    Maksimovskaya, RI
    Kovaleva, LA
    Fedotov, MA
    Grigoriev, VA
    Hill, CL
    INORGANIC CHEMISTRY, 2000, 39 (17) : 3828 - 3837
  • [23] Dual Role of H2O2 in Palladium-Catalyzed Dioxygenation of Terminal Alkenes
    Huang, Jiuzhong
    Li, Jianxiao
    Zheng, Jia
    Wu, Wanqing
    Hu, Weigao
    Ouyang, Lu
    Jiang, Huanfeng
    ORGANIC LETTERS, 2017, 19 (13) : 3354 - 3357
  • [24] Molybdovanadophosphoric acid catalyzed oxidation of hydrocarbons by H2O2 to oxygenates
    Alekar, NA
    Halligudi, SB
    Rajani, R
    Gopinathan, S
    Gopinathan, C
    REACTION KINETICS AND CATALYSIS LETTERS, 2001, 72 (01): : 169 - 176
  • [25] Molybdovanadophosphoric Acid Catalyzed Oxidation of Hydrocarbons by H2O2 to Oxygenates
    Nirupa A. Alekar
    S. B. Halligudi
    R. Rajani
    S. Gopinathan
    C. Gopinathan
    Reaction Kinetics and Catalysis Letters, 2001, 72 : 169 - 176
  • [26] Copper catalyzed oxidation of benzylic alcohols in water with H2O2
    Ahmad, Jahir Uddin
    Raisanen, Minna T.
    Leskela, Markku
    Repo, Timo
    APPLIED CATALYSIS A-GENERAL, 2012, 411 : 180 - 187
  • [27] Photocatalytic reduction of CO2 with H2O on titanium oxides prepared within zeolites and mesoporous molecular sieves
    Ikeue, K
    Yamashita, H
    Anpo, M
    ELECTROCHEMISTRY, 2002, 70 (06) : 402 - 408
  • [28] Manganese catalyzed cis-dihydroxylation of electron deficient alkenes with H2O2
    Saisaha, Pattama
    Pijper, Dirk
    van Summeren, Ruben P.
    Hoen, Rob
    Smit, Christian
    de Boer, Johannes W.
    Hage, Ronald
    Alsters, Paul L.
    Feringa, Ben L.
    Browne, Wesley R.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2010, 8 (19) : 4444 - 4450
  • [29] A new catalytic method for the selective oxidation of aniline to nitrosobenzene over titanium silicate molecular sieves, TS-1, using H2O2 as oxidant
    Selvam, T
    Ramaswamy, AV
    CHEMICAL COMMUNICATIONS, 1996, (10) : 1215 - 1216
  • [30] Titanium superoxide catalyzed selective oxidation of phenols to p-quinones with aq. H2O2
    Dewkar, GK
    Shaikh, TM
    Pardhy, S
    Kulkarni, SS
    Sudalai, A
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2005, 44 (07): : 1530 - 1532
12345