Salting-out Ability of Inorganic Salts in Solutions of Ethoxylated Nonylphenols

被引:9
|
作者
Stankova, A. V. [1 ]
Elokhov, A. M. [1 ,2 ]
Kudryashova, O. S. [2 ]
机构
[1] Perm State Natl Res Univ, Perm 614990, Russia
[2] Perm State Natl Res Univ, Inst Nat Sci, Perm 614990, Russia
关键词
phase-separating systems; nonionic surfactants; ethoxylated nonylphenols; salting-out; CLOUD POINT EXTRACTION; 2-PHASE SYSTEMS; MODEL;
D O I
10.1134/S0036024418070270
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The pattern of changes in the salting-out ability of the salts of nontransition metals and ammonium is established with respect to aqueous solutions of ethoxylated nonylphenols. The anions in the salt play a key role in the process, while cations have almost no effect on the salting-out ability of the salts of singly charged anions. The salting-out effect of anions diminishes in the order , , Cl-, , Br-, and I-. Na+, K+, , and Ba2+ cations have no pronounced salting-in effect. The salting-in effect diminishes along with the charge of the cation in the order Al3+, Mg2+, and Li+. It is shown that the salting-out ability of salts diminishes as the degree of surfactant ethoxylation grows.
引用
收藏
页码:1386 / 1391
页数:6
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