Novel O-alkyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonochloridates: Synthesis and properties

被引：1
|
作者：
Gibadullina, Elmira M. [1 ]
Azmukhanova, Ramilya R. [1 ]
Pudovik, Michael A. [1 ]
Burilov, Alexander R. [1 ]
机构：
[1] Russian Acad Sci, AE Arbuzov Inst Organ & Phys Chem, Kazan Sci Ctr, Kazan, Russia
来源：
HETEROATOM CHEMISTRY | 2017年 / 28卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1002/hc.21366
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of O,O-dialkyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonates with phosphorus pentachloride affords O-alkyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonochloridates. A transformation of O-alkyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonochloridates into diphosphonates is discovered. Base-mediated reactions of methyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonochloridates with aliphatic alcohols are studied. The reaction of alkyl (3,5-di-tert-butyl-4-hydroxybenzyl)phosphonochloridates with diethylamine gives the corresponding phosphonamides, whose oxidation results in new O-alkyl N,N-diethyl[3,5-(di-tert-butyl-4-oxocyclohexa-2,5-diene-1-ylidene)methyl]phosphonamides.
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页数：7
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