Facile synthesis of chiral isopropyl carbinols with high enantiomeric excess via catalytic enantioselective addition of diisopropylzinc to aldehydes

被引:26
|
作者
Yang, WK [1 ]
Cho, BT [1 ]
机构
[1] Hallym Univ, Dept Chem, Chunchon 200702, Kangwondo, South Korea
关键词
D O I
10.1016/S0957-4166(00)00253-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Highly effective syntheses of chiral alkyl and aryl isopropyl carbinols with high enantiomeric excess (94-98% ec) via catalytic enantioselective addition of diisopropylzinc to aldehydes have been developed. (C) 2000 Elsevier Science Ltd. All rights reserved.
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页码:2947 / 2953
页数:7
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