Synthesis and characterization of triphenylantimony(V) (O-alkyl, O-cycloalkyl and O-aryltrithiophosphates)

被引：5
|
作者：
Tripathi, UN [1 ]
Ahmad, MS [1 ]
机构：
[1] Vikram Univ, Sch Studies Chem, Ujjain 456010, Madhya Pradesh, India
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2004年 / 179卷 / 11期
关键词：
antimony; triphenylantimony (V); trithiophosphate;
D O I：
10.1080/10426500490485011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Triphenylantimony (V) (O-alkyl, O-cycloalkyl and O-aryltrithiophosphates) of the type Ph3Sb[S-2(S)P(OR)] (R = Me, Et, Pr-n, Pr-i, Bu-n, Bu-s, Bu-i, Am-i, Ph and C.h. = cyclohexyl) have been synthesized for the first time by the reaction of triphenylantimony (V) dibromide with potassium trithiophosphates in 1:1 molar ratio in methanol. These new compounds have been characterized by elemental analysis, molecular weight determinations, and spectroscopic (IR,C-13 and P-31 NMR) stuclies. On the basis of these clala trigonal bipyramidal geonteoy has been proposed for these compounds.
引用
收藏
页码：2307 / 2313
页数：7
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