Fabrication of quaternary phosphonium-intercalated vermiculite for reinforcing UV-curable epoxy acrylate coatings

被引：4
|
作者：
Liao, Huazhong [1 ]
Ma, Dong [2 ]
Jiao, Zepeng [3 ]
Xie, Yushan [1 ]
Tan, Shaozao [1 ]
Cai, Xiang [4 ]
Huang, Langhuan [1 ]
机构：
[1] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China
[2] Jinan Univ, Dept Biomed Engn, Guangzhou 510632, Guangdong, Peoples R China
[3] Jinan Univ, Analyt & Testing Ctr, Guangzhou 510632, Guangdong, Peoples R China
[4] Guangdong Polytech, Dept Light Chem Engn, Foshan 528041, Peoples R China
来源：
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY | 2015年 / 29卷 / 03期
基金：
中国国家自然科学基金;
关键词：
benzyl triphenyl phosphorus chloride; UV curable; vermiculite; epoxy acrylate; MECHANICAL-PROPERTIES; NANOCOMPOSITES; MORPHOLOGY; FIBERS; FILMS;
D O I：
10.1080/01694243.2014.980615
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
In this study, UV-curable epoxy acrylate film was reinforced with benzyl triphenyl phosphorus chloride-intercalated vermiculite (BTPC-VMT). BTPC-VMT was prepared by intercalating benzyl triphenyl phosphorus chloride (BTPC) into vermiculite (VMT) and was used as reinforcing filler. Then, X-ray diffraction and Scanning electronic microscope results of hybrid films indicated that BTPC-VMT was well dispersed in the matrix. The hybrid films displayed enhanced tensile strength, impact strength, and pencil hardness without sacrificing elongation at break. Moreover, the thermal property of hybrid films was generally improved. The resulting hybrid films are promising for a number of applications, e.g. for metal and wood for their surface protection.
引用
收藏
页码：171 / 184
页数：14
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