New polymeric materials for photonic applications: Preliminary investigations

被引:3
|
作者
Aldea, Anca [1 ]
Albu, Ana-Maria [2 ]
Rau, Ileana [1 ]
机构
[1] Univ Politehn Bucuresti, Dept Gen Chem, 1-7 Gh Polizu,Sect 1, Bucharest 011061, Romania
[2] Univ Politehn Bucuresti, Dept Bioresources & Polymer Sci, 1-7 Gh Polizu,Sect 1, Bucharest 011061, Romania
关键词
Amide; Photonics; UV-Vis spectroscopy; Chromophores; RAFT POLYMERIZATION; FUNCTIONALIZED DNA; THIN-FILMS; DERIVATIVES;
D O I
10.1016/j.optmat.2016.01.032
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper we propose two types of polymeric materials synthesized by us suitable to interact by assembling with DNA in order to obtain new NLO biomaterials. The first polymer is a methacrylic chromophore with azobenzene groups and carbazolyl sequences known for their carrying principles while the second one is a copolymer of the methacrylic chromophore with a N-substituted amide. The N-substituted amide is N-acryloyl morpholine already used in biological application and also because is compatible with DNA. Spectral characterization of these materials showed charge transfer interactions depending on the solvent. The results obtained indicate that these new polymeric/copolymeric chromophores could interact with DNA in order to obtain biomaterials for photonic applications. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:90 / 93
页数:4
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