Molecular recognition. Electrostatic effects in supramolecular self-assembly

被引：35
|
作者：
Crowley, JD [1 ]
Goshe, AJ [1 ]
Bosnich, B [1 ]
机构：
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 03期
关键词：
D O I：
10.1039/b210957c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A di-positively charged metal-based receptor is shown to form 1:1 or 2:1 association complexes with rigid, linear two-site guests depending on the site separation, suggesting that electrostatic repulsion controls the association nuclearity.
引用
收藏
页码：392 / 393
页数：2
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