Controlled Electrochemical Polymerization Strategies for Electroactive Polyaniline Thin Films

被引：9

作者：

Kharade, Rohini R. ^{[1
]}

Patil, Pallavi B. ^{[1
]}

Khot, Kishor V. ^{[1
]}

Ghanwat, Vishvnath B. ^{[1
]}

Kondalkar, Vijay V. ^{[1
]}

Bagade, Chaitali S. ^{[1
]}

Desai, N. D. ^{[1
]}

Mane, R. M. ^{[1
]}

Bhosale, P. N. ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Mat Res Lab, Kolhapur 416004, Maharashtra, India

来源：

MACROMOLECULAR SYMPOSIA | 2016年 / 362卷 / 01期

关键词：

conducting Emeraldine salt; controlled electrodeposition; FT-IR study of PANI; polyaniline thin films; RAMAN of PANI;

D O I：

10.1002/masy.201400262

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyaniline (PANI) thin films were successfully deposited using controlled electrodeposition (ED) technique from a mixed solution of 0.1M aniline and 0.5M H2SO4 on ITO coated substrate. The effect of different deposition cycles 10, 25, 50, 75, 100 on thickness, optical and morphological properties of electrodeposited PANI thin films was studied. The formation mechanism of highly conducting form of polyaniline i.e. Emeraldine salt is explained. The support of Fourier transform-infra red (FT-IR) and Raman spectroscopy was given to confirm Emeraldine salt of PANI. Further DC electrical conductivity of PANI has been measured in temperature range from 300 to 500 K using two point probe method. The optical and morphological properties of PANI give its application towards flexible electrochromic glasses.

引用

页码：7 / 10

页数：4

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