Removal of ethylenediaminetetraacetic acid and its cobalt complex by layered double hydroxide/titanium dioxide from aqueous solution

被引:2
|
作者
Sheha, Reda R. [1 ]
Harb, Ahmed H. [1 ]
El-sayed, Ibrahim El-T. [2 ]
Someda, Hanan H. [1 ]
机构
[1] Atom Energy Author, Dept Nucl Chem, Hot Labs Ctr, Cairo, Egypt
[2] Menoufia Univ, Dept Chem, Fac Sci, El Menoufia, Egypt
关键词
Mechanical mixture; Titanium; Core shell; Photocatalytic degradation; EDTA; DOUBLE HYDROXIDES; PHOTOCATALYTIC DEGRADATION; EFFICIENT PHOTOCATALYSTS; PHENOL; NANOPARTICLES; OXYANIONS; ANION; WATER; LDH;
D O I
10.1080/19443994.2015.1080193
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
TiO2-LDH photocatalysts as mechanical mixture (MCPC) and core-shell (CSPC) were successfully synthesized and characterized by XRD, TEM, and EDX techniques. The band gaps were determined by UV-vis diffuse reflectance. The photocatalytic efficiency of the catalysts for removal of ethylenediaminetetraacetic acid (EDTA) and its cobalt complexes (Co(II)-EDTA) was evaluated under ultraviolet (UV) irradiation. Results showed that the employed catalysts not only has higher removal efficiency for both EDTA and Co(II)-EDTA than TiO2, but also easily separated from the aqueous phase. Removal percentages of about 83 and 88% (for EDTA) and 71 and 81% (for Co(II)-EDTA) are achieved by MMPC and CSPC, respectively.
引用
收藏
页码:16466 / 16472
页数:7
相关论文
共 50 条
  • [31] MgCaFe-layered double hydroxide (LDH) for congo red dye removal in aqueous solution
    Soltani, Zeynab
    Salavati, Hossein
    Movahedi, Maryam
    Sadeghi, Zahra
    IRANIAN CHEMICAL COMMUNICATION, 2018, 6 (01) : 39 - 48
  • [32] Adsorption of Fluoride from Aqueous Solution on Calcined and Uncalcined Layered Double Hydroxide
    Ramirez-Llamas, L. A.
    Leyva-Ramos, R.
    Jacobo-Azuara, A.
    Martinez-Rosales, J. M.
    Isaacs-Paez, E. D.
    ADSORPTION SCIENCE & TECHNOLOGY, 2015, 33 (04) : 393 - 410
  • [33] Stable suspension of layered double hydroxide nanoparticles in aqueous solution
    Xu, ZP
    Stevenson, GS
    Lu, CQ
    Lu, GQM
    Bartlett, PF
    Gray, PP
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (01) : 36 - 37
  • [34] A Novel Cobalt Modified Layered Double Hydroxide for the Efficient Removal of Fluoride
    Noorjahan, M.
    Khayyum, M. A.
    Mangatayaru, K. Girija
    MATERIALS FOCUS, 2015, 4 (04) : 283 - 289
  • [35] Stable suspension of layered double hydroxide nanoparticles in aqueous solution
    Xu, Zhi Ping
    Stevenson, Gregory S.
    Lu, Chao-Qing
    Lu, Gao Qing
    Bartlett, Perry F.
    Gray, Peter P.
    Journal of the American Chemical Society, 2006, 128 (01): : 36 - 37
  • [36] Removal of Phosphate from Aqueous Solution Using Layered Double Hydroxide Prepared from Waste Iron-Making Slag
    Kuwahara, Yasutaka
    Tamagawa, Shigetaka
    Fujitani, Tadahiro
    Yamashita, Hiromi
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2016, 89 (04) : 472 - 480
  • [37] Removal of arsenate from aqueous solution by nanocrystalline Mg/Al layered double hydroxide: sorption characteristics, prospects, and challenges
    Goh, K. H.
    Lim, T. T.
    Dong, Z. L.
    WATER SCIENCE AND TECHNOLOGY, 2010, 61 (06) : 1411 - 1417
  • [38] Entrapment of Mg-Al layered double hydroxide in calcium alginate beads for phosphate removal from aqueous solution
    Han, Yong-Un
    Lee, Won-Suk
    Lee, Chang-Gu
    Park, Seong-Jik
    Kim, Ki-Woo
    Kim, Song-Bae
    DESALINATION AND WATER TREATMENT, 2011, 36 (1-3) : 178 - 186
  • [39] Removal of 2-chlorophenol from aqueous solution by Mg/Al layered double hydroxide (LDH) and modified LDH
    Chuang, Ya Hui
    Tzou, Yu Min
    Wang, Ming Kuang
    Liu, Cheng Hua
    Chiang, Po Neng
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2008, 47 (11) : 3813 - 3819
  • [40] Removal of sarafloxacin from aqueous solution through Ni/Al-layered double hydroxide@ZIF-8
    Davanlo, Sahar Abaskhani
    Samadi-Maybodi, Abdolraouf
    JOURNAL OF ENVIRONMENTAL HEALTH SCIENCE AND ENGINEERING, 2024, 22 (01) : 245 - 262