Design and Catalytic Application of Functional Porous Organic Polymers: Opportunities and Challenges

被引：32

作者：

Enjamuri, Nagasuresh ^{[1
]}

Sarkar, Santu ^{[2
]}

Reddy, Benjaram M. ^{[1
]}

Mondal, John ^{[1
]}

机构：

[1] Indian Inst Chem Technol, CSIR, Inorgan & Phys Chem Div, Uppal Rd, Hyderabad 500007, Andhra Pradesh, India

[2] Dumka Engn Coll, Basic Sci & Humanities Dept, Polytech Compound Rd, Dumka 814101, Jharkhand, India

来源：

CHEMICAL RECORD | 2019年 / 19卷 / 09期

关键词：

porous organic polymers (POPs); Friedel-Crafts alkylation; oxidative polymerization; polymerisation in nonaqueous medium; value-added products; ULTRAFINE PALLADIUM NANOPARTICLES; HETEROGENEOUS CATALYST; EFFICIENT; FRAMEWORKS; HYDROGENATION; ACETALIZATION; NANOCRYSTALS; SULFONATION; FABRICATION; NANOHYBRID;

D O I：

10.1002/tcr.201800080

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review article encompasses the progress and conventional overview of current research activities of porous organic polymers (POPs), especially in catalysis, as they have garnered colossal interest in the scientific fraternity due to their intriguing characteristic features. Various synthetic strategies with possible modification of functionality of POPs have been used to improve the catalytic efficiency towards value-added chemicals production. Accordingly, this review article is mainly focused on the design, development of various functionalized POPs by employing Friedel-Crafts alkylation, FeCl3 assisted oxidative polymerisation and polymerisation in nonaqueous medium, and a comprehensive understanding in potential catalytic applications namely, acetalization, hydrodeoxygenation (HDO), hydrogenation, coupling, photocatalytic hydrogen evolution and biomass conversion towards the production of value-added chemicals in biodiesel and chemical industries.

引用

页码：1782 / 1792

页数：11

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