Preparation, characterization and spectroscopic properties of difluoroboron complexes with some fluoroquinolones

被引：12

作者：

Lin, Lu ^{[1
]}

Zhai, Yunling ^{[1
]}

Wang, Dunjia ^{[1
]}

Yin, Guodong ^{[1
]}

Fan, Ling ^{[1
]}

Hu, Yanjun ^{[1
]}

机构：

[1] Hubei Normal Univ, Coll Chem & Chem Engn, Hubei Key Lab Pollutant Anal & Reuse Technol, Hubei Collaborat Innovat Ctr Rare Met Chem, Huangshi 435002, Peoples R China

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2016年 / 182卷

关键词：

Difluoroboron complexes; Fluoroquinolones; Fluorescence; Quantum yield; Spectroscopic properties; BETA-DIKETONATE DERIVATIVES; BORON DIFLUORIDE; ANTIBACTERIAL ACTIVITY; METAL-COMPLEXES; LUMINESCENCE; OFLOXACIN; QUINOLONE; AGENTS;

D O I：

10.1016/j.jfluchem.2015.11.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six novel difluoroboron complexes with fluoroquinolones were prepared from fluoroquinolones via complexation with boron trifluoride etherate in DMF-CH2Cl2 solution. Their spectroscopic properties were investigated by UV-vis absorption, FTIR, H-1 NMR and fluorescence spectroscopic techniques. The results showed that these difluoroboron complexes exhibited the intense fluorescence emission at 401579 nm under UV visible illumination and possessed a relatively high quantum yield in DMSO solution and solid state. Especially, the difluoroboron complex of Levofloxacin displayed the strongest fluorescence and highest quantum yield (Phi(u) = 0.63) in these difluoroboron complexes, due to its conjugated rigid plane system via four fused six-membered cyclic structures. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：7 / 11

页数：5

共 50 条

[31] THE PREPARATION AND CHARACTERIZATION OF SOME NITROSYL COMPLEXES OF TECHNETIUM
ORVIG, C
DAVISON, A
JONES, AG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 301 - INOR
[32] SPECTROSCOPIC PROPERTIES OF SOME MONONUCLEAR PLATINUM(II) COMPLEXES
BAILEY, JA
LOW, DW
MISKOWSKI, VM
GRAY, HB
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 333 - INOR
[33] PREPARATION AND SPECTROSCOPIC PROPERTIES OF SOME NEW ASYMMETRIC ORGANOSILANES
HOLT, A
JARVIE, AWP
JERVIS, GJ
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1973, (02): : 114 - 122
[34] Preparation and spectroscopic characterization of two manganese(II)semiquinone complexes
Barreto, WJ
Barreto, SRG
Kawano, Y
deOliveira, LFC
Di Mauro, E
Paschoal, FMM
MONATSHEFTE FUR CHEMIE, 2003, 134 (12): : 1545 - 1554
[35] Synthesis, Characterization, Electrochemistry, and Spectroscopic Properties of Some Anthracenyl Functionalized Phthalocyanine Complexes of Ruthenium(II)
Adeloye, Adewale O.
Ajibade, Peter A.
JOURNAL OF CHEMISTRY, 2014, 2014
[36] Preparation and Spectroscopic Characterization of Two Manganese(II)semiquinone Complexes
Wagner J. Barreto
Sônia R. G. Barreto
Yoshio Kawano
Luiz F. C. deOliveira
Eduardo Di Mauro
Fabiana M. M. Paschoal
Monatshefte für Chemie / Chemical Monthly, 2003, 134 : 1545 - 1554
[37] PREPARATION AND SOME PROPERTIES OF SILACYCLOPENTADIENE COMPLEXES OF COBALT
SAKURAI, H
HAYASHI, J
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 63 (DEC16) : C10 - C12
[38] PREPARATION AND PROPERTIES OF SOME OXOVANADIUM(IV) COMPLEXES
HORNER, SM
TYREE, SY
VENEZKY, DL
INORGANIC CHEMISTRY, 1962, 1 (04) : 844 - &
[39] Preparation and properties of some phthiocol inner complexes
Geyer, BP
Smith, GM
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1941, 63 : 3071 - 3075
[40] PREPARATION AND PROPERTIES OF SOME PENTAAMMINECOBALT(3) COMPLEXES
JORDAN, RB
SARGESON, AM
TAUBE, H
INORGANIC CHEMISTRY, 1966, 5 (07) : 1091 - &

← 1 2 3 4 5 →