Synthesis of oxy aminated [60] and [70]fullerenes with cumene hydroperoxide as oxidant

被引：12
|
作者：
Lemiegre, Loic
Tanaka, Takatsugu
Nanao, Takeshi
Isobe, Hiroyuki [1 ]
Nakamura, Eiichi
机构：
[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Tokyo 1130033, Japan
[3] Japan Sci & Technol Agcy, ERATO, Nakamura Funct Carbon Cluster Project, Bunkyo Ku, Tokyo 1130033, Japan
来源：
CHEMISTRY LETTERS | 2007年 / 36卷 / 01期
关键词：
D O I：
10.1246/cl.2007.20
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of [60] or [70]fullerene with excess secondary amine and 3 equiv. of cumene hydroperoxide regioselectively afforded a mono-oxygenated tetraamino or diamino fullerene in good to high yield. The reaction is operationally simple and applicable to a large-scale synthesis.
引用
收藏
页码：20 / 21
页数：2
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