Synthesis of oxy aminated [60] and [70]fullerenes with cumene hydroperoxide as oxidant

被引：12
|
作者：
Lemiegre, Loic
Tanaka, Takatsugu
Nanao, Takeshi
Isobe, Hiroyuki [1 ]
Nakamura, Eiichi
机构：
[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Tokyo 1130033, Japan
[3] Japan Sci & Technol Agcy, ERATO, Nakamura Funct Carbon Cluster Project, Bunkyo Ku, Tokyo 1130033, Japan
来源：
CHEMISTRY LETTERS | 2007年 / 36卷 / 01期
关键词：
D O I：
10.1246/cl.2007.20
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of [60] or [70]fullerene with excess secondary amine and 3 equiv. of cumene hydroperoxide regioselectively afforded a mono-oxygenated tetraamino or diamino fullerene in good to high yield. The reaction is operationally simple and applicable to a large-scale synthesis.
引用
收藏
页码：20 / 21
页数：2
相关论文
共 50 条
  • [1] POLYHYDROGENATION OF [60]-FULLERENES AND [70]-FULLERENES
    DARWISH, AD
    ABDULSADA, AK
    LANGLEY, GJ
    KROTO, HW
    TAYLOR, R
    WALTON, DRM
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1995, (12): : 2359 - 2365
  • [2] Dermal Exposure to Cumene Hydroperoxide: Assessing Its Toxic Relevance and Oxidant Potential
    Rider, Cynthia V.
    Chan, Po
    Herbert, Ron A.
    Kissling, Grace E.
    Fomby, Laurene M.
    Hejtmancik, Milton R.
    Witt, Kristine L.
    Waidyanatha, Suramya
    Travlos, Greg S.
    Kadiiska, Maria B.
    TOXICOLOGIC PATHOLOGY, 2016, 44 (05) : 749 - 762
  • [3] Estimation of the efficiency of the C60 and C70 fullerenes as inhibitors of the radical chain oxidation of cumene
    Galimov, Dim, I
    Gazeeva, Dilara R.
    Sabirov, Denis Sh
    Bulgakov, Ramil G.
    FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2023, 31 (02) : 176 - 181
  • [4] Synthesis of radiolabeled fullerenes C-60 and C-70
    Wilson, SR
    Chin, E
    FULLERENE SCIENCE AND TECHNOLOGY, 1996, 4 (01): : 43 - 48
  • [5] Intensification of Synthesis of Cumene Hydroperoxide Using Sonochemical Reactors
    Chavan, Vivek P.
    Gogate, Parag R.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (22) : 12433 - 12438
  • [6] Chlorination and arylation of [60]- and [70]fullerenes
    Birkett, PR
    Darwish, AD
    Avent, AG
    Kroto, HW
    Taylor, R
    Walton, DRM
    CHEMICAL PHYSICS OF FULLERENES 10 (AND 5) YEARS LATER: THE FAR-REACHING IMPACT OF THE DISCOVERY OF C60, 1996, 316 : 199 - 213
  • [7] 2-STAGE TECHNOLOGY OF DICUMYL PEROXIDE SYNTHESIS FROM CUMENE AND CUMENE HYDROPEROXIDE
    ZAWADIAK, J
    STEC, Z
    KULICKI, Z
    BURGHARDT, A
    GILNER, D
    PRZEMYSL CHEMICZNY, 1995, 74 (01): : 11 - 12
  • [8] Modeling of a gas-liquid phase cumene oxidation process for efficient synthesis of cumene hydroperoxide (HPOC)
    Chen, Chujun
    2019 INTERNATIONAL CONFERENCE ON ADVANCES IN CIVIL ENGINEERING, ENERGY RESOURCES AND ENVIRONMENT ENGINEERING, 2019, 330
  • [9] Covalently linked [60,70] fullerenes-nitroxide unit for synthesis and characterization
    Shi, ZQ
    Li, YL
    Xu, JH
    Ge, ZX
    Zhu, DB
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2000, 61 (07) : 1095 - 1099
  • [10] Synthesis and structure of allylated derivatives of fullerenes C60 and C70
    V. P. Gubskaya
    L. N. Islamova
    G. M. Fazleeva
    Sh. K. Latypov
    A. F. Saifina
    A. T. Gubaidullin
    D. R. Sharafutdinova
    I. A. Nuretdinov
    O. G. Sinyashin
    Russian Chemical Bulletin, 2016, 65 : 1556 - 1565
12345