Transition-Metal-Catalyzed Synthesis of Hydroxylated Arenes

被引：190
|
作者：
Alonso, Diego A. [1 ,2 ]
Najera, Carmen [1 ,2 ]
Pastor, Isidro M. [1 ,2 ]
Yus, Miguel [1 ,2 ]
机构：
[1] Univ Alicante, Dept Organ Chem, E-03080 Alicante, Spain
[2] Univ Alicante, Inst Organ Synth, E-03080 Alicante, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 18期
关键词：
C-H activation; homogeneous catalysis; hydroxylation; oxidation; phenols; C-O BOND; ARYL HALIDES; BENZOIC-ACIDS; H BONDS; OXIDATIVE FUNCTIONALIZATION; AROMATIC ACETOXYLATION; REDUCTIVE ELIMINATION; DIOXYGEN ACTIVATION; HYDROGEN-PEROXIDE; CARBON-HETEROATOM;
D O I：
10.1002/chem.201000470
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An overview of the recent bibliography in the transition-metal-catalyzed hydroxylation of aryl derivatives is presented. Two reaction protocols are considered: 1) C-H activation/hydroxylation and, 2) cross-coupling hydroxylation of aryl halides. The achievements and limitations for both procedures are described taking into consideration different metal catalyst/oxidant combinations.
引用
收藏
页码：5274 / 5284
页数：11
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