Photochemical rearrangement of 5,6-epoxy derivatives of the Diels-Alder adduct of levoglucosenone and piperylene

被引：3

作者：

Biktagirov, Ilgiz M. ^{[1
]}

Faizullina, Liliya Kh. ^{[1
]}

Salikhov, Shamil M. ^{[1
]}

Galin, Fanur Z. ^{[1
]}

Valeev, Farid A. ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Inst Chem, Ufa 450054, Russia

来源：

MENDELEEV COMMUNICATIONS | 2017年 / 27卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

CONTRACTION; 1,3-DIENES; REAKTIONEN; KETONES; RING;

D O I：

10.1016/j.mencom.2017.05.006

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of 5,6-epoxy 4-keto derivatives of the Diels-Alder adduct of levoglucosenone and piperylene in C6H6-MeOH causes cleavage of the C-4-C-5 bond giving product containing vicinal acetone and alkyl acetate moieties, the latter would further transform into 1-alkoxycarbonyl-2-hydroxy-2-methylcyclopentane derivative annulated to 5,8-dioxabicyclo[3.2.1]octane cage.

引用

页码：237 / 239

页数：3

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