Photochemical rearrangement of 5,6-epoxy derivatives of the Diels-Alder adduct of levoglucosenone and piperylene

被引：3
|
作者：
Biktagirov, Ilgiz M. [1 ]
Faizullina, Liliya Kh. [1 ]
Salikhov, Shamil M. [1 ]
Galin, Fanur Z. [1 ]
Valeev, Farid A. [1 ]
机构：
[1] Russian Acad Sci, Ufa Inst Chem, Ufa 450054, Russia
来源：
MENDELEEV COMMUNICATIONS | 2017年 / 27卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
CONTRACTION; 1,3-DIENES; REAKTIONEN; KETONES; RING;
D O I：
10.1016/j.mencom.2017.05.006
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Photolysis of 5,6-epoxy 4-keto derivatives of the Diels-Alder adduct of levoglucosenone and piperylene in C6H6-MeOH causes cleavage of the C-4-C-5 bond giving product containing vicinal acetone and alkyl acetate moieties, the latter would further transform into 1-alkoxycarbonyl-2-hydroxy-2-methylcyclopentane derivative annulated to 5,8-dioxabicyclo[3.2.1]octane cage.
引用
收藏
页码：237 / 239
页数：3
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