Reactivity, spectroscopy, and structure of reduced fullerenes

被引：8
|
作者：
Meier, MS [1 ]
Spielmann, HP
Haddon, RC
Bergosh, RG
Gallagher, ME
Hamon, MA
Weedon, BR
机构：
[1] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
[2] Univ Kentucky, Dept Biochem, Lexington, KY 40506 USA
来源：
CARBON | 2000年 / 38卷 / 11-12期
基金：
美国国家科学基金会;
关键词：
carbon nanotubes; fullerene; chromatography; nuclear magnetic resonance (NMR);
D O I：
10.1016/S0008-6223(99)00289-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Reduced fullerenes, the simplest covalent derivatives of the fullerene family of carbon allotropes, provide an excellent context for the study of the fundamental chemical reactivity of fullerenes. We have developed a general method for the formation of a number of these compounds. Using Zn(Cu) reduction, we have access to pure samples of several isomerically pure C60Hn and C70Hn species. We have completely assigned the C-13 NMR spectrum of C60H6 and have assigned the majority of the resonances in C60H2. (C) 2000 Published by Elsevier Science Ltd.
引用
收藏
页码：1535 / 1538
页数：4
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