Synthesis of optically active chiral shell dendrons

被引：21
|
作者：
Junge, DM
McGrath, DV
机构：
[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA
[2] Univ Connecticut, Inst Mat Sci, Storrs, CT 06269 USA
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 13期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0040-4039(98)00135-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We present the preparation of a series of chiral dendrons, in which chiral subunits are placed in individual generational shells at increasing distances from the focal point, by a combination of convergent and divergent dendrimer synthesis methods, Analysis of chiroptical data suggests that these dendrons do not possess conformational order in solution. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1701 / 1704
页数：4
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