(3S)-Benzyl N-(1-hydroxy-2,5-dioxo-pyrrolidin-3-yl)carbamate:: two-dimensional sheets built from O-H...O, N-H...O, C=O...C=O and C-H...O interactions linked into a three-dimensional complex framework via C-H...π(arene)interactions

被引:2
|
作者
Stefanowicz, Piotr [1 ]
Jaremko, Mariusz [1 ]
Jaremko, Lukasz [1 ]
Kochel, Andrzej [1 ]
机构
[1] Wroclaw B Beirut Univ, Fac Chem, PL-50383 Wroclaw, Poland
来源
关键词
Esters;
D O I
10.1107/S0108270107006646
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C10H12O5N2, crystallizes with two independent molecules in the asymmetric unit. The molecules in the crystal structure are arranged into one-dimensional substructural ribbon motifs stabilized by a combination of two O-H center dot center dot center dot O and three N-H center dot center dot center dot O intermolecular hydrogen bonds, and also augmented by short C=O center dot center dot center dot C=O carbonyl-carbonyl interactions. Two intermolecular C-H center dot center dot center dot O short contacts between adjacent ribbons generate complex two-dimensional sheets on the ab plane. Adjacent sheets are linked via C-H center dot center dot center dot pi(arene) interactions, resulting in a complex three-dimensional framework.
引用
收藏
页码:O204 / O206
页数:3
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