Preparation of Pt-Ru@Polypyrrole-MWNT Catalysts by γ-Irradiation and Chemical Reduction and Their Adsorption Capacity for CO

被引:9
|
作者
Bae, Hyoung-Bong [1 ]
Oh, Sang-Hyub [2 ]
Woo, Jin-Chun [2 ]
Choi, Seong-Ho [1 ]
机构
[1] Hannam Univ, BK NanoBiosensor Res Team 21, Dept Chem, Taejon 305811, South Korea
[2] Korea Res Inst Stand & Sci, Taejon 305600, South Korea
关键词
Pt-Ru Nanoparticles; Catalysts; gamma-Irradiation; Chemical Reduction; CO Stripping; CARBON NANOTUBES; SONOCHEMICAL PREPARATION; PLATINUM-RUTHENIUM; NANOPARTICLES; EFFICIENCY; AG; DISPERSION; PS; PD;
D O I
10.1166/jnn.2010.2981
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With the objective to prepare electrocatalysts with high efficiency, the Pt-Ru@PPy-MWNT catalysts were prepared by different approaches. First, the polypyrrole (PPy) as anchoring materials was coated on the surface of multi walled carbon nanotubes (MWNT) by in situ polymerization. Subsequently, Pt-Ru nanoparticles were deposited onto PPy-MWNT composite by different methods like the reduction of metal ions by gamma-irradiation and chemical reduction using formaldehyde as reducing agent assisted with stirring of magnetic bar, and assisted with microwave irradiation, and assisted with ultrasonic irradiation, in order to prepare electrocatalyst for fuel cell. The catalytic efficiency of Pt-Ru@PPy-MWNT catalyst was examined for CO stripping.
引用
收藏
页码:6901 / 6906
页数:6
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