Preparation of Pt-Ru@Polypyrrole-MWNT Catalysts by γ-Irradiation and Chemical Reduction and Their Adsorption Capacity for CO

被引:9
|
作者
Bae, Hyoung-Bong [1 ]
Oh, Sang-Hyub [2 ]
Woo, Jin-Chun [2 ]
Choi, Seong-Ho [1 ]
机构
[1] Hannam Univ, BK NanoBiosensor Res Team 21, Dept Chem, Taejon 305811, South Korea
[2] Korea Res Inst Stand & Sci, Taejon 305600, South Korea
关键词
Pt-Ru Nanoparticles; Catalysts; gamma-Irradiation; Chemical Reduction; CO Stripping; CARBON NANOTUBES; SONOCHEMICAL PREPARATION; PLATINUM-RUTHENIUM; NANOPARTICLES; EFFICIENCY; AG; DISPERSION; PS; PD;
D O I
10.1166/jnn.2010.2981
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
With the objective to prepare electrocatalysts with high efficiency, the Pt-Ru@PPy-MWNT catalysts were prepared by different approaches. First, the polypyrrole (PPy) as anchoring materials was coated on the surface of multi walled carbon nanotubes (MWNT) by in situ polymerization. Subsequently, Pt-Ru nanoparticles were deposited onto PPy-MWNT composite by different methods like the reduction of metal ions by gamma-irradiation and chemical reduction using formaldehyde as reducing agent assisted with stirring of magnetic bar, and assisted with microwave irradiation, and assisted with ultrasonic irradiation, in order to prepare electrocatalyst for fuel cell. The catalytic efficiency of Pt-Ru@PPy-MWNT catalyst was examined for CO stripping.
引用
收藏
页码:6901 / 6906
页数:6
相关论文
共 36 条
  • [1] Catalytic Efficiency of Pt-Ru-Mo/MWNT Catalysts Prepared by γ-ray Irradiation and Chemical Reduction Method in Direct Methanol Fuel Cell
    Kim, Sang-Ho
    Jeon, Ji-Ung
    Kwen, Hai-Doo
    Choi, Seong-Ho
    JOURNAL OF NANOELECTRONICS AND OPTOELECTRONICS, 2012, 7 (05) : 488 - 493
  • [2] One-step preparation of Pt-M@FP-MWNT catalysts (M = Ru, Ni, Co, Sn, and Au) by γ-ray irradiation and their catalytic efficiency for CO and MeOH
    Yang, Dae-Soo
    Sim, Kwang-Sik
    Kwen, Hai-Doo
    Choi, Seong-Ho
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (01) : 538 - 545
  • [3] An infrared study of NO and CO adsorption on zeolite-supported Ru and Ru-Pt catalysts
    Martins, RL
    Baldanza, MAS
    Schmal, M
    JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (42): : 10303 - 10307
  • [4] Radiolytic deposition of Pt-Ru catalysts on the conductive polymer coated MWNT and their catalytic efficiency for CO and MeOH
    Bae, Hyoung-bong
    Ryu, Jung-Ho
    Byun, Bok-Soo
    Choi, Seong-Ho
    Kim, Sang-Ho
    Hwang, Chul-Gyun
    MULTI-FUNCTIONAL MATERIALS AND STRUCTURES, PTS 1 AND 2, 2008, 47-50 : 1478 - +
  • [5] Preparation of Pt–Co alloy catalysts by electrodeposition for oxygen reduction in PEMFC
    Yupa Saejeng
    Nisit Tantavichet
    Journal of Applied Electrochemistry, 2009, 39 : 123 - 134
  • [6] Radiolytic Synthesis of Pt-Ru Catalysts Based on Functional Polymer- Grafted MWNT and Their Catalytic Efficiency for CO and MeOH
    Yang, Dae-Soo
    Sim, Kwang-Sik
    Kwen, Hai-Doo
    Choi, Seong-Ho
    JOURNAL OF NANOMATERIALS, 2011, 2011
  • [7] Preparation of Pt-Co alloy catalysts by electrodeposition for oxygen reduction in PEMFC
    Saejeng, Yupa
    Tantavichet, Nisit
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2009, 39 (01) : 123 - 134
  • [8] Bimetallic Ru-Pt and Pt-Co fuel cell catalysts prepared by strong electrostatic adsorption and electroless deposition
    Tengco, John Meynard
    Mehrabadi, Bahareh Alsadat Tavakoli
    Diao, Weijian
    Zhang, Yunya
    Wongkaew, Akkarat
    Garrick, Taylor
    Weidner, John
    Regalbuto, John
    Monnier, John
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [9] Adsorption of CO on Ru and Pt blacks and catalysts and the possibility of its utilization for the determination of the ruthenium-free surface
    Ivo Paseka
    Journal of Solid State Electrochemistry, 2007, 11 : 52 - 58
  • [10] Adsorption of CO on Ru and Pt blacks and catalysts and the possibility of its utilization for the determination of the ruthenium-free surface
    Paseka, Ivo
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2007, 11 (01) : 52 - 58