Optimization of transesterification of castor oil with ethanol using a central composite rotatable design (CCRD)

被引：69
|
作者：
Cavalcante, Kiany S. B. [1 ,2 ]
Penha, Maria N. C. [1 ]
Mendonca, Karlene K. M. [1 ]
Louzeiro, Hilton C. [1 ,2 ]
Vasconcelos, Antonio C. S. [1 ,2 ]
Maciel, Adeilton P. [1 ]
de Souza, Antonio G. [2 ]
Silva, Fernando C. [1 ]
机构：
[1] Univ Fed Maranhao, Lab Nucleo Biodiesel, Sao Luis, MA, Brazil
[2] Univ Fed Paraiba, Lab Combustiveis Lubrificantes & Biodiesel, BR-58059900 Joao Pessoa, Paraiba, Brazil
来源：
FUEL | 2010年 / 89卷 / 05期
关键词：
Biodiesel; Castor oil; Central composite rotatable design; RAPESEED OIL; BIODIESEL; FATS;
D O I：
10.1016/j.fuel.2009.10.029
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
In the present study, the synthesis of fatty acid esters from castor oil using an alkaline catalyst was optimized. The variables reaction time, catalyst amount and oil: ethanol molar ratio were studied using a central composite rotatable design. The effects and significance of the models on the response variable and on ethyl biodiesel yield derived from pure castor oil were evaluated using a response surface curve and analysis of variance. All the variables significantly affected the reaction yield, the amount of catalyst being the most effective. The highest yield was obtained using an oil: ethanol molar ratio of 1: 11, 1.75% KOH and a reaction time of 90 min. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1172 / 1176
页数：5
相关论文
共 50 条
  • [41] Central composite rotatable design for liquefaction of pine barks
    Açikalin, K
    Karaca, F
    Bolat, E
    FUEL PROCESSING TECHNOLOGY, 2005, 87 (01) : 17 - 24
  • [42] OPTIMIZATION OF THE SYNTHESIS OF AN ANALOG OF JOJOBA OIL USING A FULLY CENTRAL COMPOSITE DESIGN
    COTERON, A
    SANCHEZ, N
    MARTINEZ, M
    ARACIL, J
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1993, 71 (03): : 485 - 488
  • [43] 23 central composite rotatable design for the production of neem oil nanoemulsion for antifungal and antiparasitic applications
    Rabelo, Alessandra S.
    Sutili, Felipe K.
    Meneses, Juliana O.
    Severino, Patricia
    Souto, Eliana B.
    Fujimoto, Rodrigo Y.
    Cardoso, Juliana C.
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2021, 96 (08) : 2159 - 2167
  • [44] Optimization of Medium Constituents for the Production of Citric Acid from Waste Glycerol Using the Central Composite Rotatable Design of Experiments
    Ksiazek, Ewelina Ewa
    Janczar-Smuga, Malgorzata
    Pietkiewicz, Jerzy Jan
    Walaszczyk, Ewa
    MOLECULES, 2023, 28 (07):
  • [45] Optimization of microencapsulation of yellow mombin juice by spray drying using a central composite rotatable design and powder physicochemical properties
    de Moura, Naira Paes
    Silva, Jackelinne de Andrade
    Barreto de Souza, Michelle Maria
    da Silva Junior, Marcony Edson
    Azoubel, Patricia Moreira
    Converti, Attilio
    Sucupira Maciel, Maria Ines
    FOOD SCIENCE AND TECHNOLOGY, 2022, 42
  • [46] Application of a rotatable orthogonal central composite design to the optimization of the formulation and utilization of an useful plasticizer for cement
    Kamoun, A
    Samet, B
    Bouaziz, J
    Châabouni, M
    ANALUSIS, 1999, 27 (01) : 91 - 96
  • [47] Comparison of the Central Composite Rotatable Design with Doehlert Matrix on the Optimization of the Synthetic Dairy Effluent Treatment
    Muniz, Gustavo Lopes
    Borges, Alisson Carraro
    Souza, Douglas Venancio
    Fonseca da Silva, Teresa Cristina
    Batista, Rafael Oliveira
    WATER AIR AND SOIL POLLUTION, 2018, 229 (09):
  • [48] Optimization of process parameter for alpha-amylase produced by Bacillus cereus amy3 using one factor at a time (OFAT) and central composite rotatable (CCRD) design based response surface methodology (RSM)
    Saha, Shyama Prasad
    Mazumdar, Deepika
    BIOCATALYSIS AND AGRICULTURAL BIOTECHNOLOGY, 2019, 19
  • [49] Optimization of empagliflozin immediate release tablets (10 mg) using central composite rotatable design with response surface methodology
    Hanif, Anas M.
    Bushra, Rabia
    Iffat, Wajiha
    Ghayas, Sana
    Perveen, Shaheen
    Riaz, Humayun
    Alam, Shazia
    Ali, Syed Imran
    Ismail, Nahlah Elkudssiah
    Zeb-un-Nisa
    PAKISTAN JOURNAL OF PHARMACEUTICAL SCIENCES, 2021, 34 (04) : 1519 - 1525
  • [50] Comparison of the Central Composite Rotatable Design with Doehlert Matrix on the Optimization of the Synthetic Dairy Effluent Treatment
    Gustavo Lopes Muniz
    Alisson Carraro Borges
    Douglas Venâncio Souza
    Teresa Cristina Fonseca da Silva
    Rafael Oliveira Batista
    Water, Air, & Soil Pollution, 2018, 229
12345