Effect of NaCl on the excess enthalpies of binary liquid systems

被引：2

作者：

Friese, T ^{[1
]}

Schulz, S ^{[1
]}

Ulbig, P ^{[1
]}

Wagner, K ^{[1
]}

机构：

[1] Univ Dortmund, Lehrstuhl Thermodynam, D-44221 Dortmund, Germany

来源：

THERMOCHIMICA ACTA | 1998年 / 310卷 / 1-2期

关键词：

alcohol; cyclohexane; excess enthalpies; flow calorimetry; sodium chloride; water;

D O I：

10.1016/S0040-6031(97)00386-9

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The excess molar enthalpies h(1+23)(E), of ethanol+(water+NaCl), benzylalcohol+(water+NaCl), and cyclohexane+(methanol+NaCl) were measured at 298.15 K, those of methanol+(water+NaCl) at 298.15 and 323.15 K. An LKB flow microcalorimeter was used and a special flow-mix cell was developed with regard to the corrosive electrolyte solutions. Knowing the integral enthalpy of solution and the solution enthalpy at infinite dilution for a salt (3) in a solvent (2), the molar excess enthalpy h(123)(E), can be calculated. (C) 1998 Elsevier Science B.V.

引用

页码：87 / 94

页数：8

共 50 条

[21] Correlation of excess enthalpies of highly asymmetric binary systems with FRKS equation of state
Liu, Guangheng
Qu, Qing
Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 1998, 49 (02): : 229 - 234
[22] The experimental determination and correlation of excess enthalpies of binary systems of cyclohexanone with different alcohols
Ma, PS
Xia, SQ
Wu, XX
ACTA PHYSICO-CHIMICA SINICA, 2002, 18 (07) : 644 - 648
[23] Excess enthalpies for binary mixtures of formamide with dialkylacetamides
Zaichikov, AM
Golubinskii, OE
ZHURNAL FIZICHESKOI KHIMII, 1999, 73 (03): : 563 - 565
[24] EXCESS-ENTHALPIES OF BINARY POLAR MIXTURES
KRUMBECK, M
SCHULZ, S
THERMOCHIMICA ACTA, 1989, 151 : 109 - 130
[25] Excess enthalpies and excess volumes of the liquid binary mixtures of propylene carbonate plus six alkanols at 298.15 K
Francesconi, R
Comelli, F
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1996, 41 (06): : 1397 - 1400
[26] Excess enthalpies and (vapour plus liquid) equilibrium data for the binary mixtures of dimethylsulphoxide with ketones
Radhamma, M.
Venkatesu, P.
Rao, M. V. Prabhakara
Prasad, D. H. L.
JOURNAL OF CHEMICAL THERMODYNAMICS, 2007, 39 (12): : 1661 - 1666
[27] EXCESS-ENTHALPIES FOR BINARY-LIQUID MIXTURES OF CARBON-TETRACHLORIDE WITH ALCOHOLS
LUO, YS
CEN, PL
LI, BG
ZHOU, JD
ZHU, ZQ
FLUID PHASE EQUILIBRIA, 1985, 20 (MAR) : 137 - 144
[28] Liquid-phase excess enthalpies for the binary mixtures of 1-chloronaphthalene + dichloroalkanes
Comelli, Fablo, 1600, (36):
[29] Excess Enthalpies of Mixing, Effect of Temperature and Composition on the Density, and Viscosity and Thermodynamic Properties of Binary Systems of {Ammonium-Based Ionic Liquid plus Alkanediol}
Domanska, Urszula
Papis, Paulina
Szydlowski, Jerzy
Krolikowska, Marta
Krolikowski, Marek
JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (44): : 12692 - 12705
[30] EXCESS THERMODYNAMIC PROPERTIES OF BINARY-LIQUID SYSTEMS
PRAKASH, O
DARBARI, S
ACUSTICA, 1988, 65 (02): : 107 - 109

← 1 2 3 4 5 →