Synthesis and characterization of deuterium-labelled (fulvene)M(CO)3 complexes (M=Cr, Mo)

被引：7
|
作者：
Edelmann, FT [1 ]
机构：
[1] Otto Von Guericke Univ, Inst Chem, D-39106 Magdeburg, Germany
来源：
INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 15期
关键词：
deuteration; fulvenes; fulvene complexes; chromium complexes; molybdenum complexes;
D O I：
10.1016/j.ica.2004.06.038
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The preparation and characterization of a series of deuterium-labelled (fulvene)M(CO)(3) (M = Cr, Mo) complexes is reported. (eta(5)-6-Dimethylaminofulvene-d(2))Cr(CO)(3) and (eta(5)-6-dimethylaminofulvene-d(2))MO(CO)(3) were obtained in high yields by reacting the deuterated fulvene ligands with (MeCN)(3)M(CO)(3) (M=Cr, Mo). In addition, syntheses of 6,6-diphenylfulvene-d(10) and 6,6-diphenyl-1,2-benzofulvene-d(10) as well as the corresponding tricarbonylchromium complexes are described. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：4592 / 4595
页数：4
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