Synthesis and characterization of deuterium-labelled (fulvene)M(CO)3 complexes (M=Cr, Mo)

被引：7

作者：

Edelmann, FT ^{[1
]}

机构：

[1] Otto Von Guericke Univ, Inst Chem, D-39106 Magdeburg, Germany

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 15期

关键词：

deuteration; fulvenes; fulvene complexes; chromium complexes; molybdenum complexes;

D O I：

10.1016/j.ica.2004.06.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation and characterization of a series of deuterium-labelled (fulvene)M(CO)(3) (M = Cr, Mo) complexes is reported. (eta(5)-6-Dimethylaminofulvene-d(2))Cr(CO)(3) and (eta(5)-6-dimethylaminofulvene-d(2))MO(CO)(3) were obtained in high yields by reacting the deuterated fulvene ligands with (MeCN)(3)M(CO)(3) (M=Cr, Mo). In addition, syntheses of 6,6-diphenylfulvene-d(10) and 6,6-diphenyl-1,2-benzofulvene-d(10) as well as the corresponding tricarbonylchromium complexes are described. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4592 / 4595

页数：4

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