Liquid-phase acetylation of tetralin with acetyl chloride over zeolites: inhibition of the reaction by the products

被引:15
|
作者
Moreau, P
Finiels, A
Pelorgeas, S
Vigneau, O
Lasperas, M
机构
[1] Lab. de Mat. Catalytiques et C., CNRS UMR 5618, Ecl. Natl. Sup. de Chim. de M., 34296 Montpellier Cedex 5
关键词
acetylation; zeolites; tetralin; acetyltetralin; adsorption;
D O I
10.1023/A:1019044718995
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
KY and H-beta zeolites are efficient catalysts in the acetylation reaction of tetralin with acetyl chloride. Their activity depends largely on the experimental conditions and is restricted by the strong adsorption of organic species, either acetic acid or acetyltetralin formed in the reaction.
引用
收藏
页码:161 / 166
页数:6
相关论文
共 50 条
  • [21] MECHANISM OF HETEROGENEOUS LIQUID-PHASE OXIDATION OF CYCLOHEXENE, CUMENE, AND TETRALIN
    KRISHNA, LVG
    RAO, MS
    SRIVASTAVA, RD
    JOURNAL OF CATALYSIS, 1977, 49 (01) : 109 - 111
  • [22] Oriented synthesis of target products in liquid-phase tandem reaction over a tripartite zeolite capsule catalyst
    Yang, Guohui
    Kawata, Hajime
    Lin, Qihang
    Wang, Jingyan
    Jin, Yuzhou
    Zeng, Chunyang
    Yoneyama, Yoshiharu
    Tsubaki, Noritatsu
    CHEMICAL SCIENCE, 2013, 4 (10) : 3958 - 3964
  • [23] Liquid-phase hydration process of cyclohexene with zeolites
    Ishida H.
    Catalysis Surveys from Asia, 1997, 1 (2) : 241 - 246
  • [24] SYNERGISM IN INHIBITION OF STYRENE AND TETRALIN LIQUID-PHASE OXIDATION BY ORGANIC PHOSPHITES AND TRANSITION-METAL ACETYLACETONATES
    POBEDIMSKII, DG
    NASYBULLIN, SA
    KADYROVA, VK
    KIRPICHNIKOV, PA
    DOKLADY AKADEMII NAUK SSSR, 1976, 226 (03): : 634 - 636
  • [25] Liquid-phase alkylation of naphthalene by isopropanol over zeolites - Part III. Mordenites
    Cutrufello, MG
    Ferino, I
    Monaci, R
    Rombi, E
    Solinas, V
    Magnoux, R
    Guisnet, A
    APPLIED CATALYSIS A-GENERAL, 2003, 241 (1-2) : 91 - 111
  • [26] Liquid-phase oxidation of ethylamine to acetaldehyde oximes over tungsten-doped zeolites
    Ding, Jianghong
    Xu, Hao
    Wu, Haihong
    Wu, Peng
    SCIENCE CHINA-CHEMISTRY, 2017, 60 (07) : 942 - 949
  • [27] Liquid-phase oxidation of ethylamine to acetaldehyde oximes over tungsten-doped zeolites
    Jianghong Ding
    Hao Xu
    Haihong Wu
    Peng Wu
    Science China Chemistry, 2017, 60 : 942 - 949
  • [28] Diffusion kinetics of spatial distribution formation for liquid-phase reaction products
    Gorshenev, VN
    Ershov, YA
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2000, 74 : S476 - S482
  • [29] Liquid-phase oxidation of ethylamine to acetaldehyde oximes over tungsten-doped zeolites
    Jianghong Ding
    Hao Xu
    Haihong Wu
    Peng Wu
    Science China(Chemistry), 2017, (07) : 942 - 949
  • [30] Liquid-phase degradation of HDPE over alkali-treated MFI zeolites with mesopores
    Choi, Dong Ho
    Park, Ji Won
    Kim, Jong-Ho
    Sugi, Yoshihiro
    Seo, Gon
    POLYMER DEGRADATION AND STABILITY, 2006, 91 (12) : 2860 - 2866