Carbanionic Route to Electroactive Carbon-Centered Anion and Radical Oligomers

被引：6
|
作者：
Dane, Eric L. [1 ]
Swager, Timothy M. [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 19期
基金：
美国国家科学基金会;
关键词：
NON-KEKULE MOLECULE; ORGANIC POLYMERS; POLYRADICALS; TRANSISTORS; BDPA;
D O I：
10.1021/ol1017728
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of poly-1,3-bisdiphenylene-2-phenyl allyl (BDPA) radicals via a new anionic oligomerization strategy is reported. The material displays a reversible reduction from the orange-red radical to the blue carbanion in solution.
引用
收藏
页码：4324 / 4327
页数：4
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